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Award ID contains: 1855624

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  1. Abstract Ultra‐low velocity zones (ULVZs) are anomalous structures, generally associated with decreased seismic velocity and sometimes an increase in density, that have been detected in some locations atop the Earth's core‐mantle boundary (CMB). A wide range of ULVZ characteristics have been reported by previous studies, leading to many questions regarding their origins. The lowermost mantle beneath Antarctica and surrounding areas is not located near currently active regions of mantle upwelling or downwelling, making it a unique environment in which to study the sources of ULVZs; however, seismic sampling of this portion of the CMB has been sparse. Here, we examine core‐reflected PcP waveforms recorded by seismic stations across Antarctica using a double‐array stacking technique to further elucidate ULVZ structure beneath the southern hemisphere. Our results show widespread, variable ULVZs, some of which can be robustly modeled with 1‐D synthetics; however, others are more complex, which may reflect 2‐D or 3‐D ULVZ structure and/or ULVZs with internal velocity variability. Our findings are consistent with the concept that ULVZs can be largely explained by variable accumulations of subducted oceanic crust along the CMB. Partial melting of subducted crust and other, hydrous subducted materials may also contribute to ULVZ variability. 
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  2. Abstract Two large low velocity provinces (LLVPs) are observed in Earth's lower mantle, beneath Africa and the Pacific Ocean, respectively. The maximum height of the African LLVP is ∼1,000 km larger than that of the Pacific LLVP, but what causes this height difference remains unclear. LLVPs are often interpreted as thermochemical piles whose morphology is greatly controlled by the surrounding mantle flow. Seismic observations have revealed that while some subducted slabs are laterally deflected at ∼660–1,200 km, other slabs penetrate into the lowermost mantle. Here, through geodynamic modeling experiments, we show that rapid sinking of stagnant slabs to the lowermost mantle can cause significant height increases of nearby thermochemical piles. Our results suggest that the African LLVP may have been pushed more strongly and longer by surrounding mantle flows to reach a much shallower depth than the Pacific LLVP, perhaps since the Tethys slabs sank to the lowermost mantle. 
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  3. Abstract The carbon and water cycles in the Earth's interior are linked to key planetary processes, such as mantle melting, degassing, chemical differentiation, and advection. However, the role of water in the carbon exchange between the mantle and core is not well known. Here, we show experimental results of a reaction between Fe3C and H2O at pressures and temperatures of the deep mantle and core‐mantle boundary (CMB). The reaction produces diamond, FeO, and FeHx, suggesting that water can liberate carbon from the core in the form of diamond (“core carbon extraction”) while the core gains hydrogen, if subducted water reaches to the CMB. Therefore, Earth's deep water and carbon cycles can be linked. The extracted core carbon can explain a significant amount of the present‐day mantle carbon. Also, if diamond can be collected by mantle flow in the region, it can result in unusually high seismic‐velocity structures. 
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  4. Abstract The Earth's lowermost mantle is characterized by two large low shear velocity provinces (LLSVPs). The regions outside the LLSVPs have been suggested to be strongly influenced by subducted slabs and, therefore, much colder than the LLSVPs. However, localized low‐velocity seismic anomalies have been detected in the subduction‐influenced regions, whose origin remains unclear. Here, three‐dimensional geodynamic calculations are performed, and they show that linear, ridge‐like hot thermal anomalies, or thermal ridges, form in the relatively cold, downwelling regions of the lowermost mantle. Like the formation of Richter rolls due to sublithosphere small‐scale convection (SSC), the thermal ridges form as a result of SSC from the basal thermal boundary layer and they extend in directions parallel to the surrounding mantle flow. The formation of thermal ridges in subduction regions of the lowermost mantle is very sensitive to the thermal structures of the subducted materials, and thermal heterogeneities brought to the bottom of the mantle by subducting slabs greatly promote the formation of thermal ridges. The formation of thermal ridges is also facilitated by the increase of core‐mantle boundary heat flux and vigor of lowermost mantle convection. The thermal ridges may explain the low‐velocity seismic anomalies outside of the LLSVPs in the lowermost mantle. The results suggest that the relatively cold, subduction‐influenced regions of the Earth's lowermost mantle may contain localized hot anomalies. 
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  5. unknown (Ed.)
    The Earth’s core–mantle boundary presents a dramatic change in materials, from silicate to metal. While little is known about chemical interactions between them, a thin layer with a lower velocity has been proposed at the topmost outer core (Eʹ layer) that is difficult to explain with a change in concentration of a single light element. Here we perform high-temperature and -pressure laser-heated diamond-anvil cell experiments and report the formation of SiO2 and FeHx from a reaction between water from hydrous minerals and Fe–Si alloys at the pressure–temperature conditions relevant to the Earth’s core–mantle boundary. We suggest that, if water has been delivered to the core–mantle boundary by subduction, this reaction could enable exchange of hydrogen and silicon between the mantle and the core. The resulting H-rich, Si-deficient layer formed at the topmost core would have a lower density, stabilizing chemical stratification at the top of the core, and a lower velocity. We suggest that such chemical exchange between the core and mantle over gigayears of deep transport of water may have contributed to the formation of the putative Eʹ layer. 
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  6. Anomalies along Earth’s core can be explained by former oceanic seafloor that descended 3000 km to the base of the mantle. 
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