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Abstract To enhance the reaction kinetics without sacrificing activity in porous materials, one potential solution is to utilize the anisotropic distribution of pores and channels besides enriching active centers at the reactive surfaces. Herein, by designing a unique distribution of oriented pores and single crystalline array structures in the presence of abundant acid sites as demonstrated in the ZSM-5 nanorod arrays grown on monoliths, both enhanced dynamics and improved capacity are exhibited simultaneously in propene capture at low temperature within a short duration. Meanwhile, the ZSM-5 array also helps mitigate the long-chain HCs and coking formation due to the enhanced diffusion of reactants in and reaction products out of the array structures. Further integrating the ZSM-5 array with Co₃O₄nanoarray enables comprehensive propene removal throughout a wider temperature range. The array structured film design could offer energy-efficient solutions to overcome both sorption and reaction kinetic restrictions in various solid porous materials for various energy and chemical transformation applications. 

Microplastics are commonly recognized as environmental and biotic contaminants. The prevalent presence of microplastics in aquatic settings raises concerns about plastic pollution. Therefore, it is critical to develop methods that can eliminate these microplastics with low cost and high effectiveness. This review concisely provides an overview of various methods and technologies for removing microplastics from wastewater and marine environments. Dynamic membranes and membrane bioreactors are effective in removing microplastics from wastewater. Chemical methods such as coagulation and sedimentation, electrocoagulation, and sol-gel reactions can also be used for microplastic removal. Biological methods such as the use of microorganisms and fungi are also effective for microplastic degradation. Advanced filtration technologies like a combination of membrane bioreactor and activated sludge method show high microplastic removal efficiency. 

TiO 2 supported catalysts have been widely studied for the selective catalytic reduction (SCR) of NO x ; however, comprehensive understanding of synergistic interactions in multi-component SCR catalysts is still lacking. Herein, transition metal elements (V, Cr, Mn, Fe, Co, Ni, Cu, La, and Ce) were loaded onto TiO 2 nanoarrays via ion-exchange using protonated titanate precursors. Amongst these catalysts, Mn-doped catalysts outperform the others with satisfactory NO conversion and N 2 selectivity. Cu co-doping into the Mn-based catalysts promotes their low-temperature activity by improving reducibility, enhancing surface Mn 4+ species and chemisorbed labile oxygen, and elevating the adsorption capacity of NH 3 and NO x species. While Ce co-doping with Mn prohibits the surface adsorption and formation of NH 3 and NO x derived species, it boosts the N 2 selectivity at high temperatures. By combining Cu and Ce as doping elements in the Mn-based catalysts, both the low-temperature activity and the high-temperature N 2 selectivity are enhanced, and the Langmuir–Hinshelwood reaction mechanism was proved to dominate in the trimetallic Cu–Ce–5Mn/TiO 2 catalysts due to the low energy barrier. 

Nanoarray-based monolithic catalysts have been developed for various applications, including CO oxidation, hydrocarbon combustion, lean NOx trapping, and low-pressure CO2 hydrogenation. In this work, SO2 adsorption properties have been explored and evaluated on the cordierite honeycomb monoliths grown with zinc oxide nanoarray (ZnO), zinc oxide nanoarray washcoated by BaCO3 nanoparticles (ZnO/BaCO3), and manganese oxide nanowire array with cryptomelane structure (MnOx) at a temperature range from 50 °C to 425 °C. All samples showed temperature-dependent SO2 adsorption behaviors. The adsorption results revealed the performance order: MnOx > ZnO/BaCO3 > ZnO, with ~90% SO2 adsorbed in MnOx at 425 °C. Washcoated BaCO3 contributed to the improvement of SO2 adsorption in ZnO nanoarray, and the best performance displayed in MnOx may be attributed to their high specific surface area. After regeneration, nanoarrays all exhibited good thermal stability during test-regeneration cycles. No additional phase was formed in regenerated ZnO nanoarrays (ZnO-R), while BaCO3 was converted to BaSO4 in the regenerated ZnO/BaCO3 nanoarrays (ZnO/BaCO3-R), and the sulfur species (possibly MnSO4) and Mn2O3 were found in regenerated MnOx nanoarrays (MnOx-R). It is noted that small amount of sulfur species (possibly MnSO4) may promote the SO2 adsorption of MnOx-R at a lower temperature, while the formed Mn2O3 contributed to the deactivation of MnOx-R.