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Depinning of liquid droplets on substrates by flow of a surrounding immiscible fluid is central to applications such as cross-flow microemulsification, oil recovery and waste cleanup. Surface roughness, either natural or engineered, can cause droplet pinning, so it is of both fundamental and practical interest to determine the flow strength of the surrounding fluid required for droplet depinning on rough substrates. Here, we develop a lubrication-theory-based model for droplet depinning on a substrate with topographical defects by flow of a surrounding immiscible fluid. The droplet and surrounding fluid are in a rectangular channel, a pressure gradient is imposed to drive flow and the defects are modelled as Gaussian-shaped bumps. Using a precursor-film/disjoining-pressure approach to capture contact-line motion, a nonlinear evolution equation is derived describing the droplet thickness as a function of distance along the channel and time. Numerical solutions of the evolution equation are used to investigate how the critical pressure gradient for droplet depinning depends on the viscosity ratio, surface wettability and droplet volume. Simple analytical models are able to account for many of the features observed in the numerical simulations. The influence of defect height is also investigated, and it is found that, when the maximum defect slope is larger than the receding contact angle of the droplet, smaller residual droplets are left behind at the defect after the original droplet depins and slides away. The model presented here yields considerably more information than commonly used models based on simple force balances, and provides a framework that can readily be extended to study more complicated situations involving chemical heterogeneity and three-dimensional effects.more » « less
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The moving contact line between a fluid, liquid and solid is a ubiquitous phenomenon, and determining the maximum speed at which a liquid can wet/dewet a solid is a practically important problem. Using continuum models, previous studies have shown that the maximum speed of wetting/dewetting can be found by calculating steady solutions of the governing equations and locating the critical capillary number, $$Ca_{{crit}}$$ , above which no steady-state solution can be found. Below $$Ca_{{crit}}$$ , both stable and unstable steady-state solutions exist and if some appropriate measure of these solutions is plotted against $Ca$ , a fold bifurcation appears where the stable and unstable branches meet. Interestingly, the significance of this bifurcation structure to the transient dynamics has yet to be explored. This article develops a computational model and uses ideas from dynamical systems theory to show the profound importance of the unstable solutions on the transient behaviour. By perturbing the stable state by the eigenmodes calculated from a linear stability analysis it is shown that the unstable branch is an ‘edge’ state that is responsible for the eventual dynamical outcomes and that the system can become transient when $$Ca< Ca_{{crit}}$$ due to finite-amplitude perturbations. Furthermore, when $$Ca>Ca_{{crit}}$$ , we show that the trajectories in phase space closely follow the unstable branch.more » « less
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