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The demand for clean energy production and storage has increased interest in molten salt technologies, including Molten Salt Reactors (MSR). Understanding of how molten salts properties change with respect to temperature and structure is vital to establishing efficient, cost effective MSR systems. Research into these materials however has been limited due to the difficulty in accurately measuring properties of these reactive materials at elevated temperatures and controlled environment in a time efficient way. Much research has turned to molecular dynamic (MD) modeling to alleviate these issues. This research presents a custom fabricated falling ball viscometer system for measuring molten salt viscosity quickly. A model for correlating velocity to viscosity for Re < 300 was also developed for use with this system. The viscometer is demonstrated on eutectic FLiNaK and NaF-ZrF4 (53–47 mol%) up to 150 K above the respective melting points. The results are compared to MD simulations to verify their effectiveness for predicting viscosity and previously reported measurements. 

The atomic structure of FLiNaK and its evolution with temperature are examined with x-ray scattering and molecular dynamics (MD) simulations in the temperature range 460–636 °C. In accord with previous studies, it’s observed that the average nearest-neighbor (NN) cation-anion coordination number increases with increasing cation size, going from ∼4 for Li-F to ∼6.4 for K-F. In addition, we find that there is a coupled change in local coordination geometry – going from tetrahedral for Li-F to octahedral for Na to very disordered quasi-cuboidal for K. The varying geometry and coordination distances for the cation-anion pairs cause a relatively constant F-F next-nearest neighbor (NNN) distance of approximately 3.1 Å. This relatively fixed distance allows the F anions to assume an overall correlated structure very similar to that of a hard-sphere liquid with an extended radius which is beyond the normal F ion size but reflects the cation-anion coordination requirements. Careful consideration of the evolution of the experimental atomic distribution functions with increasing temperature shows that the changes in correlation at each distance can be understood within the context of broadening asymmetric neighbor distributions. Within the temperature range studied, the evolution of F-F correlations with increasing temperature is consistent with changes expected in a hard-sphere liquid simply due to decreasing density. 

State-of-the-art solar-grade silicon production is energy intensive and has a negative impact on the environment. Due to the robust and rapid growth of the Si-based photovoltaic (PV) industry, it is necessary to develop a greener technology for silicon production. Solid oxide membrane (SOM) electrolysis is a proven versatile green technology that can be developed to economically produce many important metal or metal compounds from their oxides. This work will discuss application of SOM electrolysis to produce solar-grade silicon from silica in a single-step resulting in net-zero-carbon emission. The high-temperature SOM electrolysis cell employs stable molten oxide-fluoride bath with silicon wafer cathode and stabilized zirconia membrane-based novel anodes. The cell design and process parameters are selected to enable silicon deposition on the Si wafer cathode. However, initially an electrochemical oxidation reaction occurred between silicon and oxygen that involved the cathode/flux/gas interfaces. An approach to successfully prevent this side reaction has been demonstrated. Electrochemical characterization of the SOM process is presented, and post-experimental characterization demonstrates Si deposits in the form of silicon carbide due to the use of graphite crucible and graphite current collector.