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Award ID contains: 1946346

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  1. Abstract While basaltic volcanism is dominant during rifting and continental breakup, felsic magmatism may be a significant component of some rift margins. During International Ocean Discovery Program (IODP) Expedition 396 on the continental margin of Norway, a graphite‐garnet‐cordierite bearing dacitic unit (the Mimir dacite) was recovered in two holes within early Eocene sediments on Mimir High (Site U1570), a marginal high on the Vøring Transform Margin. Here, we present a comprehensive textural, petrological, and geochemical study of the Mimir dacite in order to assess its origin and discuss the geodynamic implications. The major mineral phases (garnet, cordierite, quartz, plagioclase, alkali feldspar) are hosted in a fresh rhyolitic, vesicular, glassy matrix that is locally mingled with sediments. The major element chemistry of garnet and cordierite, the presence of zircon inclusions with inherited cores, and thermobarometric calculations all support an upper crustal metapelitic origin. While most magma‐rich margin models favor crustal anatexis in the lower crust, thermobarometric calculations performed here show that the Mimir dacite was produced at upper‐crustal depths (<5 kbar, 18 km depth) and high temperature (750–800°C) with up to 3 wt% water content. In situ U‐Pb analyses on zircon inclusions give a magmatic crystallization age of 54.6 ± 1.1 Ma, consistent with emplacement that post‐dates the Paleocene‐Eocene Thermal Maximum. Our results suggest that the opening of the Northeast Atlantic was associated with a phase of low‐pressure, high‐temperature crustal anatexis preceding the main phase of magmatism. 
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  2. We present computational modeling outcomes for bilithologic (peridotite and pyroxenite) mantle melting in divergent environments, considering equilibrium and disequilibrium porous flow melting of 0–50 % pyroxenite in thermal equilibrium with peridotite, potential temperatures of 1300 and 1400 °C, upwelling rates from 1–50 cm yr−1, maximum porosities of 0.1–2.0 %, and four compositions that span pyroxenite melting behavior. Basalt-like pyroxenites (G2) uniquely produce low (226Ra/230Th) and (231Pa/235U) with high (230Th/238U), but quantities greater than ~10 % produce anomalously thick crust, restricting their global abundance. Silica-deficient pyroxenite (M7-16 and MIX1G) melts are more moderate, but require chemical re-equilibration during transport to resemble global basalts, while hybrid lithologies (KG1) produce melts similar to those of peridotites. Uranium-series disequilibria in partial melts can also be decoupled from trace elements by radioactive decay in two-dimensional regimes. The mantle must thus contain multiple types of pyroxenite on a global scale, with melts traveling by complex networks and experiencing heterogeneous extents of chemical re-equilibration. 
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  3. Mantle heterogeneity has a first-order control of the petrological and geochemical differences of erupted mafic lavas worldwide. Whether this heterogeneity reflects only chemical variations or also lithological heterogeneity in source regions is debated. Because of their contrasted partitioning behaviors between mantle phases, First Row Transition Elements (FRTEs) are considered as potential lithological tracers. Using a combination of published data on natural and experimental samples and new high current microprobe analyses on a variety of pyroxenite samples, we investigated the parameters that control FRTE exchange coefficients (Kd) between common mantle minerals and performed inverse modeling to test if FRTE ratios from oceanic basalt compositions can be used to solve for modal proportions in their mantle source. We applied the Kd determined from mantle lithologies in this study, along with experimental melt-mineral partitioning coefficients and a simplified melting model, on two basalt suites selected for their contrasted Mn/Fe and Zn/Fe ratios. Our results show that a same FRTE ratio can be explained by a range of modal proportions in the source. However, when combined, FRTE ratios become a powerful tool to constrain the nature of the source. 
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