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Award ID contains: 1954939

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  1. ; ; ; ; ; ; (, Organometallics)
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  2. ; ; (, Journal of the American Chemical Society)
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  3. ; (, Chemical Science)
    A mild, convenient coupling of aliphatic aldehydes and unactivated alkyl bromides has been developed. The catalytic system features the use of a common Ni( ii ) precatalyst and a readily available bioxazoline ligand and affords silyl-protected secondary alcohols. The reaction is operationally simple, utilizing Mn as a stoichiometric reductant, and tolerates a wide range of functional groups. The use of 1,5-hexadiene as an additive is an important reaction parameter that provides significant benefits in yield optimizations. Initial mechanistic experiments support a mechanism featuring an alpha-silyloxy Ni species that undergoes formal oxidative addition to the alkyl bromide via a reductive cross-coupling pathway. 
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  4. ; ; (, Organic Letters)
    null (Ed.)
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