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Abstract The tropical Pacific influences climate patterns across the globe, yet robust constraints on decadal to centennial‐scale climate variations are difficult to extract from sparse instrumental observations in this region. Oxygen isotope (δ¹⁸O) records from long‐lived corals enable the quantitative reconstruction of tropical Pacific climate variability and trends over the twentieth century and beyond, but such corals are exceedingly rare. Here, we use multiple short coral δ¹⁸O records to create a coral ‘ensemble’ reconstruction of twentieth century climate in the central tropical Pacific. Ten U/Th‐dated fossil coral δ¹⁸O records from Kiritimati Island (2°N, 157°W) span 1891 CE to 2006 CE, with the younger samples enabling quantitative comparison to a large ensemble of modern coral records and instrumental sea surface temperature. A composite record constructed of modern and fossil Kiritimati coral δ¹⁸O records shows a shift toward warmer and fresher conditions from 1970 CE onward, consistent with previously published records in this region. 

Cave carbonate minerals are an important terrestrial paleoclimate archive. A few studies have explored the potential for applying carbonate clumped isotope thermometry to speleothems as a tool for constraining past temperatures. To date, most papers utilizing this method have focused on mass-47 clumped isotope values (Δ47) at a single location and reported that cave carbonate minerals rarely achieve isotopic equilibrium, with kinetic isotope effects (KIEs) attributed to CO2 degassing. More recently, studies have shown that mass-47 and mass-48 CO2 from acid digested carbonate minerals (Δ47 and Δ48) can be used together to assess equilibrium and probe KIEs. Here, we examined 44 natural and synthetic modern cave carbonate mineral samples from 13 localities with varying environmental conditions (ventilation, water level, pCO2, temperature) for (dis)equilibrium using Δ47-Δ48 values, in concert with traditional stable carbon (δ13C) and oxygen (δ18O) isotope ratios. Data showed that 19 of 44 samples exhibited Δ47-Δ48 values indistinguishable from isotopic equilibrium, and 18 (95 %) of these samples yield Δ47-predicted temperatures within error of measured modern temperatures. Conversely, 25 samples exhibited isotopic disequilibria, 13 of which yield erroneous temperature estimates. Within some speleothemsamples, we find Δ47-Δ48 values consistent with CO2 degassing effects, however, the majority of sampleswith KIEs are consistent with other processes being dominant. We hypothesize that these values reflect isotopicbuffering effects on clumped isotopes that can be considerable and cannot be overlooked. Using a Raleigh Distillation Model, we examined carbon and oxygen isotope exchange trajectories and their relationships with dual clumped isotope disequilibria. Carbon isotope exchange is associated with depletion of both Δ47 and Δ48 relative to equilibrium, while oxygen isotope exchange is associated with enrichment of both Δ47 and Δ48 relative to equilibrium. Cave rafts collected from proximate locations in Mexico exhibit the largest averagedepartures from equilibrium (ΔΔ47 = − 0.032 ± 0.007, ΔΔ48 = − 0.104 ± 0.035, where ΔΔi is the measured value – the equilibrium value). This study shows how the Δ47-Δ48 dual carbonate clumped isotope framework can be applied to a variety of tcave carbonate mineral samples, enabling identification of isotopic equilibria and therefore quantitative application of clumped isotope thermometry for paleoclimate reconstruction, or alternatively, constraining the mechanisms of kinetic effects. 

The eastern branch of the East African Rift System hosts many shallow modern lakes and paleolakes, which can be sensitive recorders of changing climate conditions (complicated by tectonics) during the past few million years. However, many of such lakes are saline–alkaline (salty and high pH), and these conditions do not easily preserve pollen and other biologically derived paleoclimate indicators. Fortunately, some preserved minerals that formed in these extreme environments reflect subtle shifts in lake water chemistry (controlled by changes in climate conditions) and therefore provide a continuous record of local and regional climate change. We present two different mineral proxies (zeolites and clays) from two different paleolake basins (Olduvai Gorge, Tanzania, and Chew Bahir, Ethiopia) as examples. 

We present new mineralogical and geochemical data from modern sediments in the Chew Bahir basin and catchment, Ethiopia. Our goal is to better understand the role of modern sedimentary processes in chemical proxy formation in the Chew Bahir paleolake, a newly investigated paleoclimatic archive, to provide environmental context for human evolution and dispersal. Modern sediment outside the currently dry playa lake floor have higher SiO 2 and Al 2 O 3 (50–70 wt.%) content compared to mudflat samples. On average, mudflat sediment samples are enriched in elements such as Mg, Ca, Ce, Nd, and Na, indicating possible enrichment during chemical weathering (e.g., clay formation). Thermodynamic modeling of evaporating water in upstream Lake Chamo is shown to produce an authigenic mineral assemblage of calcite, analcime, and Mg-enriched authigenic illitic clay minerals, consistent with the prevalence of environments of enhanced evaporative concentration in the Chew Bahir basin. A comparison with samples from the sediment cores of Chew Bahir based on whole-rock MgO/Al 2 O 3 , Ba/Sr and authigenic clay mineral δ 18 O values shows the following: modern sediments deposited in the saline mudflats of the Chew Bahir dried out lake bed resemble paleosediments deposited during dry periods, such as during times of the Last Glacial Maximum and Younger Dryas stadial. Sediments from modern detrital upstream sources are more similar to sediments deposited during wetter periods, such as the early Holocene African Humid Period. 

Lake Magadi is an internally-drained, saline and alkaline terminal sump in the southern Kenya Rift. Geochemistry of samples from a ~200-m core representing the past ~1 Myr of the lake’s history show some of the highest concentrations of transition metals and metalloids ever reported from lacustrine sediment, including redox-sensitive elements Mo, As, and V. Elevated concentrations of these elements represent times when the lake’s hypolimnion was euxinic – that is, anoxic, saline, and sulfide-rich. Euxinia was common over the past ~700 ka, tending to occur during intervals of high orbital eccentricity. These were likely times when high frequency hydrologic changes favored repeated episodes of euxinia and sulfide precipitation. High-amplitude environmental fluctuations at peak eccentricity likely impacted water balance in terrestrial habitats and resource availability for early hominins. These are associated with important events in human evolution, including the first appearance of Middle Stone Age technology between about 500 and 320 ka in the southern Kenya Rift.