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In this paper we develop a material index for selecting alloys resistant to frictional ignition in high pressure oxygen environments. A previous ignition-resistance metric proposed by NASA WSTF varies strongly and unpredictably with test conditions, thus limiting its usefulness. The material index developed here incorporates key material properties that strongly influence ignition behaviors, including friction coefficient, ignition temperature, and thermal effusivity. Finite element simulations were used to compute ignition temperatures for 15 alloys based on published frictional ignition data from NASA White Sands Testing Facility (WSTF). These values were used with the material index to construct property diagrams for ranking the materials based on their intrinsic frictional ignition resistance. The results demonstrate that nickel-based superalloys with low iron content are less likely to ignite under frictional heating than ferrous alloys and nickel-based superalloys with high content iron. The material index is then used to predict material performance outside of the test conditions, highlighting the effect of ambient temperature on nominal ignition resistance. We conclude by developing an empirical relation between ignition temperature and enthalpy of oxidation which can guide design of new ignition-resistant alloys.