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  1. Abstract

    This study integrated spatially distributed field observations and soil thermal models to constrain the impact of frozen ground on snowmelt partitioning and streamflow generation in an alpine catchment within the Niwot Ridge Long‐Term Ecological Research site, Colorado, USA. The study area was comprised of two contrasting hillslopes with notable differences in topography, snow depth and plant community composition. Time‐lapse electrical resistivity surveys and soil thermal models enabled extension of discrete soil moisture and temperature measurements to incorporate landscape variability at scales and depths not possible with point measurements alone. Specifically, heterogenous snowpack thickness (~0–4 m) and soil volumetric water content between hillslopes (~0.1–0.45) strongly influenced the depths of seasonal frost, and the antecedent soil moisture available to form pore ice prior to freezing. Variable frost depths and antecedent soil moisture conditions were expected to create a patchwork of differing snowmelt infiltration rates and flowpaths. However, spikes in soil temperature and volumetric water content, as well as decreases in subsurface electrical resistivity revealed snowmelt infiltration across both hillslopes that coincided with initial decreases in snow water equivalent and early increases in streamflow. Soil temperature, soil moisture and electrical resistivity data from both wet and dry hillslopes showed that initial increases in streamflow occurred prior to deep soil water flux. Temporal lags between snowmelt infiltration and deeper percolation suggested that the lateral movement of water through the unsaturated zone was an important driver of early streamflow generation. These findings provide the type of process‐based information needed to bridge gaps in scale and populate physically based cryohydrologic models to investigate subsurface hydrology and biogeochemical transport in soils that freeze seasonally.

     
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  2. Internal water storage within trees can be a critical reservoir that helps trees overcome both short- and long-duration environmental stresses. We monitored changes in internal tree water storage in a ponderosa pine on daily and seasonal scales using moisture probes, a dendrometer, and time-lapse electrical resistivity imaging (ERI). These data were used to investigate how patterns of in-tree water storage are affected by changes in sapflow rates, soil moisture, and meteorologic factors such as vapor pressure deficit. Measurements of xylem fluid electrical conductivity were constant in the early growing season while inverted sapwood electrical conductivity steadily increased, suggesting that increases in sapwood electrical conductivity did not result from an increase in xylem fluid electrical conductivity. Seasonal increases in stem electrical conductivity corresponded with seasonal increases in trunk diameter, suggesting that increased electrical conductivity may result from new growth. On the daily scale, changes in inverted sapwood electrical conductivity correspond to changes in sapwood moisture. Wavelet analyses indicated that lag times between inverted electrical conductivity and sapflow increased after storm events, suggesting that as soils wetted, reliance on internal water storage decreased, as did the time required to refill daily deficits in internal water storage. We found short time lags between sapflow and inverted electrical conductivity with dry conditions, when ponderosa pine are known to reduce stomatal conductance to avoid xylem cavitation. A decrease in diel amplitudes of inverted sapwood electrical conductivity during dry periods suggest that the ponderosa pine relied on internal water storage to supplement transpiration demands, but as drought conditions progressed, tree water storage contributions to transpiration decreased. Time-lapse ERI- and wavelet-analysis results highlight the important role internal tree water storage plays in supporting transpiration throughout a day and during periods of declining subsurface moisture. 
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  3. null (Ed.)
    High concentrations of trace metal(loid)s exported from abandoned mine wastes and acid rock drainage pose a risk to the health of aquatic ecosystems. To determine if and when the hyporheic zone mediates metal(loid) export, we investigated the relationship between streamflow, groundwater–stream connectivity, and subsurface metal(loid) concentrations in two ~1-km stream reaches within the Bonita Peak Mining District, a US Environmental Protection Agency Superfund site located near Silverton, Colorado, USA. The hyporheic zones of reaches in two streams—Mineral Creek and Cement Creek—were characterized using a combination of salt-tracer injection tests, transient-storage modeling, and geochemical sampling of the shallow streambed (<0.7 m). Based on these data, we present two conceptual models for subsurface metal(loid) behavior in the hyporheic zones, including (1) well-connected systems characterized by strong hyporheic mixing of infiltrating stream water and upwelling groundwater and (2) poorly connected systems delineated by physical barriers that limit hyporheic mixing. The comparatively large hyporheic zone and high hydraulic conductivities of Mineral Creek created a connected stream–groundwater system, where mixing of oxygen-rich stream water and metal-rich groundwater facilitated the precipitation of metal colloids in the shallow subsurface. In Cement Creek, the precipitation of iron oxides at depth (~0.4 m) created a low-hydraulic-conductivity barrier between surface water and groundwater. Cemented iron oxides were an important regulator of metal(loid) concentrations in this poorly connected stream–groundwater system due to the formation of strong redox gradients induced by a relatively small hyporheic zone and high fluid residence times. A comparison of conceptual models to stream concentration–discharge relationships exhibited a clear link between geochemical processes occurring within the hyporheic zone of the well-connected system and export of particulate Al, Cu, Fe, and Mn, while the poorly connected system did not have a notable influence on metal concentration–discharge trends. Mineral Creek is an example of a hyporheic system that serves as a natural dissolved metal(loid) sink, whereas poorly connected systems such as Cement Creek may require a combination of subsurface remediation of sediments and mitigation of upstream, iron-rich mine drainages to reduce metal export. 
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