skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Search for: All records

Award ID contains: 2018561

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. The structure of the title compound, C30H42N4O2, has orthorhombic (Pbca) symmetry. This compound comprises a 4-amino-1,8-naphthalimide core with a 2,2,6,6-tetramethyl-4-piperidinyl substituent bonded to each nitrogen atom. The structure displays N—H...O hydrogen bonding. The structure exhibits disorder of the main molecule. 
    more » « less
  2. The synthesis and the crystal structure of 1 H -imidazole-1-methanol, C 4 H 6 N 2 O, are described. This compound comprises an imidazole ring with a methanol group attached at the 1-position affording an imine nitrogen atom able to receive a hydrogen bond and an alcohol group able to donate to a hydrogen bond. This imidazole methanol crystallizes with monoclinic ( P 2 1 / n ) symmetry with three symmetry-unique molecules. These three molecules are connected via O—H...N hydrogen bonding in a head-to-tail configuration to form independent three-membered macrocycles. 
    more » « less
  3. This report describes the synthesis of five new colorful 6-aryldibenzo[b,d]pyrylium cation salts, a largely unexplored structural unit. These rare compounds are benzannulated structural derivatives of the well-known flavylium cations found widespread in natural pigments. These new dyes are directly compared to three previously synthesized 6-aryldibenzo[b,d]pyrylium cation salts as well as eight colorful isomeric 9-aryldibenzo[b,e]pyrylium cation, or 9-arylxanthylium, salts. The 9-arylxanthylium unit is commonly found in the biologically important rhodamine and rosamine dyes, yet six of the analogs presented in this study were either previously unreported or not isolated. The visual and spectroscopic properties of all 16 compounds were analyzed as a function of the structural differences between the compounds. All compounds displayed reversible halochromism in organic solution, displaying bright colors under acidic conditions and becoming colorless under basic conditions. 
    more » « less