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Abstract The redox state of arc mantle has been considered to be more oxidized and diverse than that of the mid-ocean ridge, but the cause of the variation is debated. We examine the redox state of the Cenozoic global arc mantle by compiling measured/calculatedfO₂of olivine-hosted melt inclusions from arc magma and modeledfO₂based on V/Sc and Cu/Zr ratios of arc basaltic rocks. The results indicate that the redox state of Cenozoic arc mantle is latitude dependent, with less oxidized arc mantle in the low latitudes, contrasting with a near constant across-latitude trend in the mid-ocean ridges. We propose that such a latitude-dependent pattern in the arc mantle may be controlled by the variation in the redox state of subducted sediment, possibly related to a latitudinal variation in the primary production of phytoplankton, which results in more organic carbon and sulfide deposited on the low-latitude ocean floor. Our findings provide evidence for the impact of the surface environment on Earth’s upper mantle. 

Abstract The Frontal Cordillera is a first‐order geologic feature of the southern central Andes, hosting the highest hinterland topography above the modern Pampean flat‐slab segment. The timing of Frontal Cordillera exhumation is important for testing models of Andean tectonics, yet large latitudinal gaps exist between structural and thermochronological constraints for the region. We conducted a thermochronometric study using a 4.4 km age‐elevation transect along the northeast ridge of Cerro Mercedario, the highest peak in the La Ramada massif at ∼32°S. Zircon (U‐Th)/He dates indicate partial resetting, supporting a limited magnitude of exhumation in even the most extreme Andean topography. Single grain apatite (U‐Th‐Sm)/He dates range from 8.5 ± 0.9 to 35.8 ± 3.6 Ma, with median dates of ∼10.5 to ∼15.7 Ma with increasing elevation. Integrated with geologic mapping and thermal history modeling, these data suggest Early to Middle Miocene exhumation along the Santa Cruz and Espinacito faults concomitant with uplift of the La Ramada massif. New apatite helium data from the Cordillera del Tigre segment of the Frontal Cordillera are partially reset and preferred modeling interpretations suggest exhumation ca. 11–9 Ma, coeval with shortening in the eastward adjacent Precordillera. These data add to accumulating regional evidence for out‐of‐sequence deformation during the Miocene, consistent with internal (hinterland) growth of a subcritical orogenic wedge contemporaneous with surface uplift and crustal thickening in the south‐central Andes. 

Abstract The Frontal Cordillera is a first‐order geologic feature of the southern central Andes, hosting the highest hinterland topography above the modern Pampean flat‐slab segment. The timing of Frontal Cordillera exhumation is important for testing models of Andean tectonics, yet large latitudinal gaps exist between structural and thermochronological constraints for the region. We conducted a thermochronometric study using a 4.4 km age‐elevation transect along the northeast ridge of Cerro Mercedario, the highest peak in the La Ramada massif at ∼32°S. Zircon (U‐Th)/He dates indicate partial resetting, supporting a limited magnitude of exhumation in even the most extreme Andean topography. Single grain apatite (U‐Th‐Sm)/He dates range from 8.5 ± 0.9 to 35.8 ± 3.6 Ma, with median dates of ∼10.5 to ∼15.7 Ma with increasing elevation. Integrated with geologic mapping and thermal history modeling, these data suggest Early to Middle Miocene exhumation along the Santa Cruz and Espinacito faults concomitant with uplift of the La Ramada massif. New apatite helium data from the Cordillera del Tigre segment of the Frontal Cordillera are partially reset and preferred modeling interpretations suggest exhumation ca. 11–9 Ma, coeval with shortening in the eastward adjacent Precordillera. These data add to accumulating regional evidence for out‐of‐sequence deformation during the Miocene, consistent with internal (hinterland) growth of a subcritical orogenic wedge contemporaneous with surface uplift and crustal thickening in the south‐central Andes. 

Abstract Lithospheric foundering is an important mechanism of crustal deformation and recycling, basin subsidence, and surface uplift in orogenic systems. The Arizaro Basin, in the Puna region of NW Argentina, is a place where foundering was proposed to have taken place during the late Miocene. The Arizaro Basin has been described as a “bobber” basin produced by Miocene lithospheric foundering. The geometry, sedimentology, deformation, and paleoelevation history of the Arizaro Basin and surrounding arc suggest dynamic processes associated with lithospheric removal. Although analogue and numerical models support this hypothesis, the history of crustal thickness in response to lithospheric removal remains unconstrained. Here, we used a novel approach exploiting the geochemistry of detrital zircons from volcanic ashes intercalated within the Arizaro Basin stratigraphy to reconstruct the paleocrustal thickness of the neighboring magmatic sources throughout the Cenozoic. Our data indicate that the sources of volcanism for the Arizaro Basin were characterized by relatively thick crust (~53 km) since ca. 36 Ma. Thickening between ca. 20 and 13 Ma and thinning after ca. 13 Ma are consistent with formation and subsequent removal of a crustal root under the nearby arc and Aguas Calientes caldera. 

Abstract The Southern Puna plateau in the central Andes has a complicated tectonic history that includes episodes of distributed shortening and extension, lithospheric delamination, uplift and Quaternary backarc volcanism. In this study, the upper crustal structure and present‐day deformation in this area is investigated using a new regional earthquake catalog derived with a deep‐learning‐based phase picker. Results show abundant strike‐slip seismicity at shallow depths in the eastern Southern Puna plateau that reveals active fault systems in the area and indicates N‐S extension/E‐W compression that changes orientation and relative magnitude from north to south. A broad zone of seismic quiescence in the western plateau may indicate a zone of upper crustal decoupling from large‐scale deformation. The region separating the western and eastern plateau exhibits a complex stress field that can be related to the boundary of east/west oriented middle‐to‐lower crustal flow in the main volcanic arc. Southeast of the plateau in the Sierras Pampeanas, crustal seismicity deepens and is dominated by conjugate reverse faulting structures associated with the direction of plate convergence. Vp and Vs seismic velocity models of the upper crust obtained through local earthquake tomography with the improved seismic catalog show low‐velocity anomalies near intermontane basins, except in the Antofagasta basin where a high‐velocity anomaly possibly represents shallow intrusive component of Quaternary basaltic volcanism. Below the Cerro Galan caldera, an upper crustal 10‐day long earthquake swarm is observed which may indicate local stress perturbations from fluids at the top of the crustal magmatic system that feeds this volcano. 

Abstract The Manantiales basin contains >4 km of nonmarine sedimentary strata that accumulated at 31.75–32.5°S during construction of the High Andes. We report field and analytical data from the underexplored northern portion of this basin. The basin contains upper Eocene–middle Miocene strata that accumulated in back‐bulge or distal foredeep through inner‐wedge‐top depozones of the Andean foreland basin as it migrated through this region. A revised accumulation history for the basin‐filling Río de los Patos and Chinches Formations supports a regional pattern of flexure in front of an east‐vergent orogenic wedge. The former formation consists of eolian and localized fluviolacustrine deposits which accumulated between ca. 38 Ma and ≤34 Ma during thrust belt development in Chile. A subsequent ≤12 Myr hiatus may reflect passage of the flexural forebulge or cessation of subsidence during orogenic quiescence. The overlying Chinches Formation records a transition from the foredeep to wedge‐top depozones. Foredeep deposits of east‐flowing, meandering streams were incised prior to ca. 18 Ma, after which deposits of axial rivers, playas, and perennial lakes ponded in a depression behind orogenic topography to the east. After ca. 15 Ma, alluvial‐fan deposits were syndepositionally deformed adjacent to growing thrust‐belt structures along the western basin margin. Although the basin record supports a westward step in the locus of deformation during Early–Middle Miocene time, it conflicts with models involving west‐vergence of the orogenic wedge. Rather, this pattern can be explained as out‐of‐sequence deformation alternating with wedge forward propagation, consistent with Coulomb wedge models incorporating syntectonic sedimentation. 

Abstract High‐relief glacial valleys shape the modern topography of the Southern Patagonian Andes, but their formation remains poorly understood. Two Miocene plutonic complexes in the Andean retroarc, the Fitz Roy (49°S) and Torres del Paine (51°S) massifs, were emplaced between 16.9–16.4 Ma and 12.6–12.4 Ma, respectively. Subduction of oceanic ridge segments initiated ca. 16 Ma at 54°S, leading to northward opening of a slab window with associated mantle upwelling. The onset of major glaciations caused drastic topographic changes since ca. 7 Ma. To constrain the respective contributions of tectonic‐mantle dynamics and fluvio‐glacial erosion to rock exhumation and landscape evolution, we perform inverse thermal modeling of a new data set of zircon and apatite (U‐Th)/He from the two massifs, complemented by apatite⁴He/³He data for Torres del Paine. Our results show rapid rock exhumation recorded only in the Fitz Roy massif between 10 and 8 Ma, which we ascribe to local mantle upwelling forcing surface uplift and intensified erosion around 49°S. Both massifs record a pulse of rock exhumation between 7 and 4 Ma, which we interpret as enhanced erosion during the beginning of Patagonian glaciations. After a period of erosional and tectonic quiescence in the Pliocene, increased rock exhumation since 3–2 Ma is interpreted as the result of alpine glacial valley carving promoted by reinforced glacial‐interglacial cycles. This study highlights that glacial erosion was the main driver to rock exhumation in the Patagonian retroarc since 7 Ma, but that mantle upwelling might be a driving force to rock exhumation as well. 

Abstract Convergent plate boundaries are key sites for continental crustal formation and recycling. Quantifying the evolution of crustal thickness and paleoelevation along ancient convergent margins represents a major goal in orogenic system analyses. Chemical and in some cases isotopic compositions of igneous rocks formed in modern supra‐subduction arcs and collisional belts are sensitive to Moho depths at the location of magmatism, implying that igneous suites from fossil orogens carry information about crustal thickness from the time they formed. Several whole‐rock chemical parameters correlate with crustal thickness, some of which were calibrated to serve as “mohometers,” that is, quantitative proxies of paleo‐Moho depths. Based on mineral‐melt partition coefficients, this concept has been extended to detrital zircons, such that combined chemical and geochronological information extracted from these minerals allows us to reconstruct the crustal thickness evolution using the detrital archive. We discuss here the mohometric potential of a variety of chemical and isotopic parameters and show that their combined usage improves paleocrustal thickness estimates. Using a MATLAB^®app developed for the underlying computations, we present examples from the modern and the deeper time geologic record to illustrate the promises and pitfalls of the technique. Since arcs are in isostatic equilibrium, mohometers are useful in reconstructing orogenic paleoelevation as well. Our analysis suggests that many global‐scale correlations between magma composition and crustal thickness used in mohometry originate in the sub‐arc mantle; additional effects resulting from intracrustal igneous differentiation depend on the compatible or incompatible behavior of the involved parameters. 

Abstract The timing of crustal thickening in the northern Central Andean Plateau (CAP), at 13–20°S, and its relationship to surface uplift is debated. Zircon qualitatively records crustal thickness as its trace element chemistry is controlled by the growth of cogenetic minerals and relative uptake of light and heavy Rare Earth Elements. Jurassic to Neogene zircons from volcanic rocks, sandstones, and river sediments reveal shifts in trace element ratios suggesting major crustal thickening at 80–55 Ma and 35–0 Ma, coincident with high‐flux magmatism. An intervening magmatic lull due to shallow subduction obscures the magmatic record from 55 to 35 Ma during which thickening continued via crustal shortening. Protracted thickening since the Late Cretaceous correlates with early elevation gain of the CAP western margin, but contrasts with Miocene establishment of near modern elevation in the northern CAP and the onset of hyperaridity along the Pacific coast, highlighting their complex spatial and temporal relationship. 

Titanite (CaTiSiO5) is a commonly occurring and versatile accessory mineral with broad applications in petrochronology. In situ U-Pb and trace element analyses via SIMS and LA-ICPMS are routinely performed using a matrix-matched reference material for U-Pb and standard glasses (non-matrix matched reference material) for elemental abundance determination. We report U-Pb isotopic ratios and major and trace element concentrations for three titanite samples (Ecstall, McClure and FCT) which are commonly used as reference materials in petrochronology studies. In addition, we characterize two new samples which can potentially serve as matrixmatched reference materials for titanite trace element geochemistry (BLR-2 and BRA-1). Based on electron microprobe analysis, samples BLR-1 and BLR-2 are homogeneous and suitable for use as a primary reference material for trace element concentrations. Whereas Ecstall, McClure, and FCT titanite reference materials show high intra-grain heterogeneity, yielding relative standard deviations for most trace elements between 5% and 40%, with higher standard deviations for U of 70% for Ecstall (n = 26), 265% for McClure (n = 22), and 202% for FCT (n = 26). Therefore, we suggest that these grains are unsuited to serve as reference materials for trace element quantification. The BRA-1 titanite has low trace element concentrations and is chemically heterogeneous (total REE abundances of 40 ppm for the rim and 95 ppm for the core of the grain), thus is not suitable for standardization of chemical composition using LA-ICPMS. It is commonly asserted that a matrix-matched standardization provides a more robust downhole fractionation correction compared to a non-matrix matched standardization. However, it remains unclear which standardization approach (matrix-matched vs non-matrix matched/glass) is more accurate for titanite trace element quantification. To resolve this, we tested several standardization approaches for trace element quantification, comparing matrix-matched (BLR-1) and nonmatrix- matched (NIST612) standardizations with different internal elemental standards (IES; Ca, Si and Ti) and without internal standardization (semi-quantitative). To provide an independent constraint on the accuracy of the various trace element standardization techniques we compared results to trace element concentrations obtained via solution Q-ICPMS on crushed BLR-2 and BRA-1 aliquots. The matrix-matched standardization using Si as the IES yields the best reproducibility of trace element concentrations followed by the matrix-matched reduction using Ti as the IES. Moreover, the matrix-matched semi-quantitative correction yielded the lowest weighted percentage of difference compared to reference trace composition quantified by solution ICPMS. Finally, in this contribution we also benchmark sampling-size for precise U-Pb dating of common-Pb rich phases like titanite.