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With the rapid urbanization and growing energy use intensity in the built environment, the glazed curtainwall has become ever more important in the architectural practice and environmental stewardship. Besides its energy efficiency roles, window has been an important transparent component for daylight penetration and a view-out for occupant satisfaction. In response to the climate crisis caused by the built environment, this research focuses on the study of net-zero energy retrofitting by using a new building integrated photovoltaic (BIPV) curtainwall as a sustainable alternative to conventional window systems. Design variables such as building orientations, climate zones, energy attributes of BIPV curtainwalls, and glazed area were studied, to minimize energy consumption and discomfort hours for three cities representing hot (Miami, FL), mixed (Charlotte, NC), and cold (Minneapolis, MN). Parametric analysis and Pareto solutions are presented to provide a comprehensive explanation of the correlation between design variables and performance objectives for net-zero energy retrofitting applications.