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  1. ; ; ; ; ; ; ; ; (, Chemistry – A European Journal)
    Abstract In this work, we describe the easy synthesis of mercury complexes with the 1,5,9‐trimesityldipyrromethene (MesDPM) ligand. The compounds were characterized using standard analytic methods such as NMR, IR, as well as UV/Vis spectroscopy. The molecular structures in solid state were determined by single‐crystal X‐ray diffraction analysis (SC‐XRD) experiments. In addition, the199Hg NMR chemical shifts were determined by measurements and quantum chemical calculations. 
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  2. ; ; ; ; ; ; (, Chemistry – A European Journal)
    Abstract Reaction of [CuH(PPh3)]6with 1 equiv. of Tl(OTf) results in formation of [Cu6TlH6(PPh3)6][OTf] ([1]OTf]), which can be isolated in good yields. Variable‐temperature1H NMR spectroscopy, in combination with density functional theory (DFT) calculations, confirms the presence of a rare Tl−H orbital interaction. According to DFT, the1H chemical shift of the Tl‐adjacent hydride ligands of[1]+includes 7.7 ppm of deshielding due to spin‐orbit effects from the heavy Tl atom. This study provides valuable new insights into a rare class of metal hydrides, given that[1][OTf]is only the third isolable species reported to contain a Tl−H interaction. 
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  3. ; ; ; ; ; ; (, Inorganic Chemistry)
    Free, publicly-accessible full text available February 17, 2026
  4. ; ; (, Inorganic Chemistry)
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