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Award ID contains: 2117699

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  1. ; ; ; (, The Journal of Organic Chemistry)
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  2. ; (, Sensors & Diagnostics)
    The near-IR fluorescent biosensor is highly selective and sensitive in responding to the hypoxic microenvironment of tumors, demonstrating high efficiency in detecting tumor hypoxia and the capability of distinguishing tumors of different sizes. 
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  3. ; ; ; ; (, ACS Applied Materials & Interfaces)
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  4. ; ; (, Catalysts)
    Manganese has attracted significant recent attention due to its abundance, low toxicity, and versatility in catalysis. In the present study, a series of manganese (III) complexes supported by salan ligands have been synthesized and characterized, and their activity as catalysts in the hydrosilylation of carbonyl compounds was examined. While manganese (III) chloride complexes exhibited minimal catalytic efficacy without activation of silver perchlorate, manganese (III) azide complexes showed good activity in the hydrosilylation of carbonyl compounds. Under optimized reaction conditions, several types of aldehydes and ketones could be reduced with good yields and tolerance to a variety of functional groups. The possible mechanisms of silane activation and hydrosilylation were discussed in light of relevant experimental observations. 
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