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  1. The monumental challenge associated with food waste management has emphasized the dire need of upcycling it into useful materials, including ultraporous adsorbent. Among various technologies of maximizing porosity of such waste-derived porous sorbents, potassium hydroxide (KOH) activation of food waste hydrochar has emerged to be a prominent one. There are two different ways to synthesize ultraporous adsorbent, namely, direct chemical activation (DCA) and char impregnation (CI). This study aims in investigating the environmental impact comparison of DCA and CI using life cycle assessment (LCA). The results demonstrate that CI processes in an environmentally sound way for synthesizing ultraporous carbons from food waste, where freshwater ecotoxicity (57.2%) plays the major contributing role in environmental impact category, primarily due to acid neutralization in the mixer unit of the CI technique of activation. In addition, the dryer unit in the CI process, which is powered by natural gas combustion, was responsible for climate change impact category. Therefore, as an alternative, employment of renewable solar energy (from solar thermal power plant) was also investigated, and results highlighted the possibility of achieving reduced climate change and acidification potential. 
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    Free, publicly-accessible full text available October 6, 2024
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  4. Shrimp shell is a popularly consumed seafood around the globe which generates a substantial quantity of solid wet waste. Hydrothermal carbonization (HTC) could be a viable pathway to convert wet shrimp shell waste into energy-dense hydrochar. The present study aims to assess the fuel properties, physicochemical attributes, and combustion properties of shrimp shell hydrochar generated with a wide range of HTC temperatures (110–290 °C). Results showed that a rise in carbonization rate results in a decline in mass yield to as low as 25.7% with the increase in HTC temperature. Thermogravimetric analysis indicates shrimp shell hydrochars to be more thermally stable than raw dried feedstock. Results from the bomb calorimeter report a maximum HHV of 27.9 MJ/kg for SS-290, showing a 13% increase in energy densification compared to raw shrimp shell. The slagging and fouling indices determined for the hydrochars further assisted in addressing the concern regarding increasing ash content changing from 17.0% to 36.6%. Lower ratings of the slagging index, fouling index, alkali index, and chlorine content for hydrochars at higher temperature indicate the reduced probability of reactor fouling during combustion. The findings of the analysis demonstrate that HTC is a promising approach for transforming shrimp shell waste into a potential fuel replacement.

     
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    Free, publicly-accessible full text available July 1, 2024
  5. Hydrofluorocarbons (HFC) are fluorinated compounds used globally for refrigeration. These gases have been shown to contain a greenhouse potential of up to 22,000 times that of CO2. Thus, 1298 type-5 deep eutectic solvents (DES) were examined for the absorption and interaction mechanisms of difluoromethane (R32), due to their non-polar attributes. Of these solvents, quaternary ammonium salts mixed with various species of hydrogen bond donators (HBD) produced the most favorable interactions, with ln activity coefficients predicted to be as low as −1.39 at 1:1 compositional ratio. These DES were further studied for compositional analysis where pure tetrabutylammonium bromide showed the strongest interaction potential. The pressure study showed a linear solubility increase with a pressure increase reaching up to 86 mol/mol% in a methyltrioctylammonium bromide and polyethylene glycol mixture at 9 bar. The van der Waals interaction is the driving force of absorption with ~3x enthalpic release over hydrogen bonding. All chemicals contain strong potential for an environmentally friendly solution, as is evident through an environmental health and safety analysis.

     
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    Free, publicly-accessible full text available May 1, 2024
  6. Free, publicly-accessible full text available May 1, 2024
  7. Hydrothermal carbonization (HTC) is a prominent thermochemical technology that can convert high-moisture waste into a valuable product (called hydrochar) at a relatively mild treatment condition (180–260 °C and 2–10 MPa). With rapidly growing research on HTC and hydrochar in recent years, review articles addressing the current and future direction of this research are scarce. Hence, this article aims to review various emerging applications of hydrochars, e.g., from solid fuel to soil amendment, from electron storage to hydrogen storage, from dye adsorption, toxin adsorption, heavy metal adsorption to nutrient recovery, and from carbon capture to carbon sequestration, etc. This article further provides an insight in the hydrochar’s working mechanism for various applications and how the applications can be improved through chemical modification of the hydrochar. Finally, new perspectives with appropriate recommendations have been made to further unveil potential applications and its improvement through hydrochar and its modified version.

     
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  8. In this study, the effect of hydrothermal liquefaction (HTL) of waste PVC was investigated in the presence of acidic hydrochar. The hydrochar was prepared by hydrothermal carbonization of pineapple waste at 250 °C and at 1 h in the presence of citric acid. Hydrochar was acidic, stable, and porous and contained acidic functional groups. Hydrochar was co-fed with PVC during HTL to enhance HTL conversion and quality of the plastic crude oil. HTL experiments were performed at 300–350 °C, 0.25–4 h of reaction times, and 0–20 wt% hydrochar-to-PVC ratio. The plastic crude oil was separated from the solid residue to evaluate HTL conversion and to analyze elemental compositions, boiling point distribution, alteration of chemical bonds, and chemical compositions. The results showed that acidic hydrochar enhances HTL conversion with a maximum value of 28.75 at 5 wt% hydrochar content at 350 °C and 0.5 h. Furthermore, plastic crude oils contained no chloride but contained significantly high carbon and hydrogen, resulting in a higher heating value of up to 36.43 MJ/kg. The major component of the plastic crude oil was 3, 5 dimethylphenol produced ranging from 61.4 to 86.4% (percentage of total identified area) according to gas chromatography mass spectroscopy (GCMS) data.

     
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  9. In this study, carbon dots are synthesized hydrothermally from loblolly pine using top-down and bottom-up processes. The bottom-up process dialyzed carbon dots from hydrothermally treated process liquid. Meanwhile, hydrochar was oxidized into carbon dots in the top-down method. Carbon dots from top-down and bottom-up processes were compared for their yield, size, functionality, and quantum properties. Furthermore, hydrothermal treatment temperature and residence time were evaluated on the aforementioned properties of carbon dots. The results indicate that the top-down method yields higher carbon dots than bottom-up in any given hydrothermal treatment temperature and residence time. The size of the carbon dots decreases with the increase in reaction time; however, the size remains similar with the increase in hydrothermal treatment temperature. Regarding quantum yield, the carbon dots from the top-down method exhibit higher quantum yields than bottom-up carbon dots where the quantum yield reaches as high as 48%. The only exception of the bottom-up method is the carbon dots prepared at a high hydrothermal treatment temperature (i.e., 260 °C), where relatively higher quantum yield (up to 18.1%) was observed for the shorter reaction time. Overall, this study reveals that the properties of lignocellulosic biomass-derived carbon dots differ with the synthesis process as well as the processing parameters. 
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