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  1. ; ; ; ; (, Angewandte Chemie International Edition)
    Abstract Ketones are among the most useful functional groups in organic synthesis, and they are commonly encountered in a broad range of compounds with various applications. Herein, we describe the mesoionic carbene‐catalyzed coupling reaction of aldehydes with non‐activated secondary and even primary alkyl halides. This metal‐free method utilizes deprotonated Breslow intermediates derived from mesoionic carbenes (MICs), which act as super electron donors and induce the single‐electron reduction of alkyl halides. This mild coupling reaction has a broad substrate scope and tolerates many functional groups, which allows to prepare a diversity of simple ketones as well as bio‐active molecules by late‐stage functionalization. 
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  2. ; ; ; ; ; ; ; (, Chemical Science)
    Base-controlled formation of Breslow intermediatesversusBreslow enolates has been achieved with mesoionic carbenes. Of particular interest is the coupling of aldehydes and alkyl halides to yield ketonesviaan ionic pathway. 
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    Free, publicly-accessible full text available May 28, 2026
  3. ; ; ; ; ; (, Organic Chemistry Frontiers)
    Chiral NHCs have found numerous applications as ligands for transition metals and in their own right for asymmetric catalysis. We report a synthetic route froml-malic acid to enantiopure 1,2,3-triazoliums with the chiral center in a fused ring. 
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    Full Text Available 
  4. ; ; ; ; (, The Journal of Organic Chemistry)
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  5. ; ; ; ; ; ; ; (, Chem Catalysis)
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