Hybrid metal‐halide perovskites (MHPs) have shown remarkable optoelectronic properties as well as facile and cost‐effective processability. With the success of MHP solar cells and light‐emitting diodes, MHPs have also exhibited great potential as gain media for on‐chip lasers. However, to date, stable operation of optically pumped MHP lasers and electrically driven MHP lasers—an essential requirement for MHP laser's insertion into chip‐scale photonic integrated circuits—is not yet demonstrated. The main obstacles include the instability of MHPs in the atmosphere, rudimentary MHP laser cavity patterning methods, and insufficient understanding of emission mechanisms in MHP materials and cavities. This review aims to provide a detailed overview of different strategies to improve the intrinsic properties of MHPs in the atmosphere and to establish an optimal MHP cavity patterning method. In addition, this review discusses different emission mechanisms in MHP materials and cavities and how to distinguish them.
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Abstract Perovskite light‐emitting diodes (PeLEDs) are advancing because of their superior external quantum efficiencies (EQEs) and color purity. Still, additional work is needed for blue PeLEDs to achieve the same benchmarks as the other visible colors. This study demonstrates an extremely efficient blue PeLED with a 488 nm peak emission, a maximum luminance of 8600 cd m−2, and a maximum EQE of 12.2% by incorporating the double‐sided ethane‐1,2‐diammonium bromide (EDBr2) ligand salt along with the long‐chain ligand methylphenylammonium chloride (MeCl). The EDBr2successfully improves the interaction between 2D perovskite layers by reducing the weak van der Waals interaction and creating a Dion–Jacobson (DJ) structure. Whereas the pristine sample (without EDBr2) is inhibited by small stacking number (
n ) 2D phases with nonradiative recombination regions that diminish the PeLED performance, adding EDBr2successfully enables better energy transfer from smalln phases to largern phases. As evidenced by photoluminescence (PL), scanning electron microscopy (SEM), and atomic force microscopy (AFM) characterization, EDBr2improves the morphology by reduction of pinholes and passivation of defects, subsequently improving the efficiencies and operational lifetimes of quasi‐2D blue PeLEDs. -
A miniature on-chip laser is an essential component of photonic integrated circuits for a plethora of applications, including optical communication and quantum information processing. However, the contradicting requirements of small footprint, robustness, single-mode operation, and high output power have led to a multi-decade search for the optimal on-chip laser design. During this search, topological phases of matter—conceived initially in electronic materials in condensed matter physics—were successfully extended to photonics and applied to miniature laser designs. Benefiting from the topological protection, a topological edge mode laser can emit more efficiently and more robustly than one emitting from a trivial bulk mode. In addition, single-mode operation over a large range of excitation energies can be achieved by strategically manipulating topological modes in a laser cavity. In this Perspective, we discuss the recent progress of topological on-chip lasers and an outlook on future research directions.