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Abstract Early Cretaceous ichthyosaurs were globally distributed pelagic marine reptiles, but many remains are fragmentary, creating a Northern Hemisphere diversity bias. A rich Hauterivian locality near the Tyndall Glacier inside Torres del Paine National Park in southern Chile yields important new data regarding ichthyosaurian diversity along the Pacific margin of Gondwana. These new data will contribute to clarifying questions regarding ichthyosaur taxonomy and the palaeobiogeographical relationships between the southern Gondwanan and Northern Hemisphere ichthyosaur groups during the Early Cretaceous. Here, we describe three new ichthyosaur specimens from this locality. Two of them are referred to Myobradypterygius hauthali, expanding the distribution of this species from the Barremian of Argentina to the Hauterivian of the Chilean Patagonia. This material shows that M. hauthali differs from Platypterygius platydactylus in forefin construction and scapular morphology, supporting its classification as a separate genus within Platypterygiinae. The third specimen is a large-bodied indeterminate ophthalmosaurine ichthyosaur. This record represents the southernmost record of Ophthalmosaurinae and the first occurrence of this group from the Cretaceous of the Southern Hemisphere. These discoveries show that ophthalmosaurines and platypterygiines continued to occur sympatrically in southernmost Gondwana during the Early Cretaceous, expanding the pattern documented in Europe to the Pacific region. 

U-Pb zircon geochronology and isotopic records have played an influential role in our understanding of convergent margin dynamics. Orogenic cyclicity models link tectonic regimes with magmatic isotopic signatures in advancing orogens, relating compressional regimes with evolved signatures and extension with juvenile signatures; however, such frameworks may not apply for retreating orogens, which commonly produce substantial crustal heterogeneities during backarc rifting and ocean spreading. We explore the Mesozoic to Cenozoic Patagonian Andes tectonic evolution, combining U-Pb zircon ages, bulk rock εNd, and new detrital zircon εHf from the retroarc basin to understand the associated magmatic arc evolution during retreat and advance of the margin. Our results reveal a protracted phase of isotopically juvenile magmatism between 150 and 80 Ma, which began during backarc extension and persisted long after the margin switched to a contractional regime. We propose that the prolonged juvenile isotopic trend started mainly due to trenchward migration of the arc during backarc extension (150−120 Ma) and persisted due to partial melting of underthrusted juvenile attenuated and oceanic crust during backarc basin closure (120−80 Ma). This interpretation implies that tectonic stress alone does not predict isotopic trends, and factors like assimilation or the composition of underthrusted crust are important controls on magmatic isotopic composition, especially in retreating and transitional orogens. 

Abstract. The loss of radiogenic Pb from zircon is known to be a major factor that can cause inaccuracy in the U–Pb geochronological system; hence, there is a need to better characterize the distribution of Pb loss in natural samples. Treatment of zircon by chemical abrasion (CA) has become standard practice in isotope dilution–thermal ionization mass spectrometry (ID-TIMS), but CA is much less commonly employed prior to in situ analysis via laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) or secondary ionization mass spectrometry (SIMS). Differentiating the effects of low levels of Pb loss in Phanerozoic zircon with relatively low-precision in situ U–Pb dates, where the degree of Pb loss is insufficient to cause discernible discordance, is challenging. We show that U–Pb isotopic ratios that have been perturbed by Pb loss may be modeled by convolving a Gaussian distribution that represents random variations from the true isotopic value stemming from analytical uncertainty with a distribution that characterizes Pb loss. We apply this mathematical framework to model the distribution of apparent Pb loss in 10 igneous samples that have both non-CA LA-ICP-MS or SIMS U–Pb dates and an estimate of the crystallization age, either through CA U–Pb or 40Ar/39Ar geochronology. All but one sample showed negative age offsets that were unlikely to have been drawn from an unperturbed U–Pb date distribution. Modeling apparent Pb loss using the logit–normal distribution produced good fits with all 10 samples and showed two contrasting patterns in apparent Pb loss; samples where most zircon U–Pb dates undergo a bulk shift and samples where most zircon U–Pb dates exhibited a low age offset but fewer dates had more significant offset. Our modeling framework allows comparison of relative degrees of apparent Pb loss between samples of different age, with the first and second Wasserstein distances providing useful estimates of the total magnitude of apparent Pb loss. Given that the large majority of in situ U–Pb dates are acquired without the CA treatment, this study highlights a pressing need for improved characterization of apparent Pb-loss distributions in natural samples to aid in interpreting non-CA in situ U–Pb data and to guide future data collection strategies.