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Titanium Phosphinidene and Phosphide Moieties from Oxidative Phosphorylation and Desilylation

https://doi.org/10.1021/jacs.4c12242

Mohar, Jacob S; Bhunia, Mrinal; Laughlin, Alexander L; Ozarowski, Andrew; Krzystek, J; Keller, Taylor M; Gau, Michael R; Lancaster, Kyle M; Telser, Joshua; Mindiola, Daniel J (April 2025, Journal of the American Chemical Society)

Free, publicly-accessible full text available April 9, 2026
Divergent Reactivity of Azides and Diazoalkanes Toward Ferrous Complexes and Isolation of a Fe ^III Carbene Radical Complex

https://doi.org/10.1021/acs.organomet.4c00471

Zars, Ethan; Pick, Lisa; Kankanamge, Achala; Gau, Michael R; Carroll, Patrick J; MacMillan, Samantha N; Lancaster, Kyle M; Meyer, Karsten; Mindiola, Daniel J (January 2025, Organometallics)

Free, publicly-accessible full text available January 27, 2026
Tellurolate: an effective Te-atom transfer reagent to prepare the triad of group 5 metal bis(tellurides)

https://doi.org/10.1039/D3SC03470D

Senthil, Shuruthi; Kwon, Seongyeon; Kong, Richard Y.; MacMillan, Samantha N.; Zatsepin, Pavel; Gau, Michael R.; Carroll, Patrick J.; Baik, Mu-Hyun; Lancaster, Kyle M.; Mindiola, Daniel J. (November 2023, Chemical Science)

We show in this work how lithium tellurolate Li(X)_nTeCH₂SiMe₃(X = THF,n= 1, 1; X = 12-crown-4,n= 2, 2), can serve as an effective Te-atom transfer reagent to all group 5 transition metal halide precursors irrespective of their oxidation state.
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