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1. Oxygen Incorporation in the Molecular Beam Epitaxy Growth of Sc _x Ga _1−x N and Sc _x Al _1−x N

   https://doi.org/10.1002/pssb.201900612  

   Casamento, Joseph; Xing, Huili Grace; Jena, Debdeep (January 2020, physica status solidi (b))

   Secondary‐ion mass spectrometry (SIMS) is used to determine impurity concentrations of carbon and oxygen in two scandium‐containing nitride semiconductor multilayer heterostructures: Sc_xGa_1−xN/GaN and Sc_xAl_1−xN/AlN grown by molecular beam epitaxy (MBE). In the Sc_xGa_1−xN/GaN heterostructure grown in metal‐rich conditions on GaN–SiC template substrates with Sc contents up to 28 at%, the oxygen concentration is found to be below 1 × 10¹⁹ cm⁻³, with an increase directly correlated with the scandium content. In the Sc_xAl_1−xN–AlN heterostructure grown in nitrogen‐rich conditions on AlN–Al₂O₃template substrates with Sc contents up to 26 at%, the oxygen concentration is found to be between 10¹⁹and 10²¹ cm⁻³, again directly correlated with the Sc content. The increase in oxygen and carbon takes place during the deposition of scandium‐alloyed layers. 

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2. Between carbide and nitride MAX phases: sol–gel assisted synthesis and characterization of the carbonitride phase Cr ₂ GaC _1−x N _x

   https://doi.org/10.1039/D4TC00067F  

   Kubitza, Niels; Huck, Isabel; Pazniak, Hanna; Kalha, Curran; Koch, David; Zhao, Bo; Thakur, Pardeep K; Lee, Tien-Lin; Riaz, Aysha A; Donner, Wolfgang; et al (June 2024, Journal of Materials Chemistry C)

   The combination of a sol–gel precursor approach and microwave heating leads to a hitherto unknown MAX phase Cr₂GaC_1−xN_x. Magnetic measurements reveal that the susceptibility depends on the nitrogen amount on the X-site. 

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3. Constraining the H ₂ column densities in the diffuse interstellar medium using dust extinction and H I data

   https://doi.org/10.1051/0004-6361/202347968  

   Skalidis, R; Goldsmith, P F; Hopkins, P F; Ponnada, S B (February 2024, Astronomy & Astrophysics)

   Context. Carbon monoxide (CO) is a poor tracer of H₂in the diffuse interstellar medium (ISM), where most of the carbon is not incorporated into CO molecules, unlike the situation at higher extinctions. Aims. We present a novel, indirect method for constraining H₂column densities (N_H2) without employing CO observations. We show that previously recognized nonlinearities in the relation between the extinction,A_V(H₂), derived from dust emission and the H Icolumn density (N_H I) are due to the presence of molecular gas. Methods. We employed archival (N_H2) data, obtained from the UV spectra of stars, and calculatedA_V(H₂) toward these sight lines using 3D extinction maps. The following relation fits the data: logN_H2= 1.38742 (logA_V(H₂)⁾³− 0.05359 (logA_V(H₂)⁾²+ 0.25722 logA_V(H₂) + 20.67191. This relation is useful for constrainingN_H2in the diffuse ISM as it requires onlyN_H Iand dust extinction data, which are both easily accessible. In 95% of the cases, the estimates produced by the fitted equation have deviations of less than a factor of 3.5. We constructed aN_H2map of our Galaxy and compared it to the CO integrated intensity (W_CO) distribution. Results. We find that the average ratio (X_CO) betweenN_H2andW_COis approximately equal to 2 × 10²⁰cm⁻²(K km s⁻¹)⁻¹, consistent with previous estimates. However, we find that theX_COfactor varies by orders of magnitude on arcminute scales between the outer and the central portions of molecular clouds. For regions withN_H2≳ 10²⁰cm⁻², we estimate that the average H₂fractional abundance,f_H2= 2N_H2/(2N_H2+N_H I), is 0.25. Multiple (distinct) largely atomic clouds are likely found along high-extinction sightlines (A_V≥ 1 mag), hence limitingf_H2in these directions. Conclusions. More than 50% of the lines of sight withN_H2≥ 10²⁰cm⁻²are untraceable by CO with aJ= 1−0 sensitivity limitW_CO= 1 K km s⁻¹. 

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4. One-dimensional temperature measurement of supersonic jet flow by resonantly ionized photoemission thermometry of molecular nitrogen

   https://doi.org/10.1364/OPTCON.543309  

   Clark, Aleksander; McCord, Walker; Pride, Kyle; Zhang, Zhili (December 2024, Optics Continuum)

   As the field of fluid dynamics progresses, the demand for sophisticated diagnostic methods to accurately assess flow conditions rises. In this work, resonantly ionized photoemission thermometry (RIPT) has been used to directly target and ionize diatomic nitrogen (N₂) to measure one-dimensional (1D) temperature profiles in a supersonic jet flow. This technique can be considered non-intrusive as the premise uses resonantly enhanced multiphoton ionization (REMPI) to target molecular nitrogen. This resonance excites N₂into absorption bands of the P, Q, and R rotational branches of N₂(b¹Π_u). The ideal (3 + 1) REMPI scheme excites from the ground state and ionizes N₂(b¹Π_u←X¹Σ_g⁺) where de-excitation results in photoemission from the first negative band of ionizedN₂⁺(B²Σ_u⁺→X²Σ_g⁺) as nitrogen returns to the ground state. The resulting emission can be observed using an intensified camera, thus permitting inference of the rotational temperature of ground-state molecular nitrogen. A linearly regressive Boltzmann distribution is applied based on previous calibration data for this technique to quantify the temperature along the ionized line. This work applies this technique to a pure N₂supersonic jet in cross-flow and counter-flow orientations to demonstrate N₂RIPT’s applications in a supersonic flow. Temperature variations are observed at different locations downstream of the exit in cross-flow, and axisymmetric in counter-flow, to generate profiles characterizing the flow dynamics. Due to the collisional effects resulting from the number density of N₂at higher pressures, a (3 + 2) REMPI scheme is observed throughout this text. 

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5. Synthesis and characterization of modular polyphosphonate homopolymers and copolymers

   https://doi.org/10.1002/pol.20200066  

   Totsch, Timothy R.; Stanford, Victoria L.; Klep, Oleksander; Burdette, Mary K.; Grant, Benjamin; Foulger, Stephen H.; Gray, Gary M. (June 2020, Journal of Polymer Science)

   Abstract Linear polyphosphonates with the generic formula –[P(Ph)(X)OR′O]_n– (X = S or Se) have been synthesized by polycondensations of P(Ph)(NEt₂)₂and a diol (HOR′OH = 1,4‐cyclohexanedimethanol, 1,4‐benzenedimethanol, tetraethylene glycol, or 1,12‐dodecanediol) followed by reaction with a chalcogen. Random copolymers have been synthesized by polycondensations of P(Ph)(NEt₂)₂and mixture of two of the diols in a 2:1:1 mol ratio followed by reaction with a chalcogen. Block copolymers with the generic formula –[P(Ph)(X)OR′O]_(x + 2)–[P(Ph)(X)OR′O]_(x + 3)– (X = S or Se) have been synthesized by the polycondensations of Et₂N[P(Ph)(X)OR′O]_(x + 2)P(Ph)NEt₂oligomers with HOR′O[P(Ph)(X)OR′O]_(x + 3)H oligomers followed by reaction with a chalcogen. The Et₂N[P(Ph)(X)OR′O]_(x + 2)P(Ph)NEt₂oligomers are prepared by the reaction of an excess of P(Ph)(NEt₂)₂with a diol while the HOR′O[P(Ph)(X)OR′O]_(x + 3)H oligomers are prepared by the reaction of P(Ph)(NEt₂)₂with an excess of the diol. In each case the excess, x is the same and determines the average block sizes. All of the polymers were characterized using¹H,¹³C{¹H}, and³¹P{¹H} NMR spectroscopy, TGA, DSC, and SEC.³¹P{¹H} NMR spectroscopy demonstrates that the random and block copolymers have the expected arrangements of monomers and, in the case of block copolymers, verifies the block sizes. All polymers are thermally stable up to ~300°C, and the arrangements of monomers in the copolymers (block vs. random) affect their degradation temperatures andT_gprofiles. The polymers have weight average MWs of up to 3.8 × 10⁴ Da. 

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