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  1. We investigate the collective non-Markovian dynamics of two fully excited two-level atoms coupled to a one-dimensional waveguide in the presence of delay. We demonstrate that analogous to the well-known superfluorescence phenomena, where an inverted atomic ensemble synchronizes to enhance its emission, there is a “subfluorescence” effect that synchronizes the atoms into an entangled dark state depending on the interatomic separation. The phenomenon can lead to a two-photon bound state in the continuum. Our results are pertinent to long-distance quantum networks, presenting a mechanism for spontaneous entanglement generation between distant quantum emitters.

    Published by the American Physical Society2024 
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    Free, publicly-accessible full text available May 1, 2025