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Generalizable Organic-to-Aqueous Phase Transfer of a Au ₁₈ Nanocluster with Luminescence Enhancement and Robust Photocatalysis in Water

https://doi.org/10.1021/acsnano.4c18197

Liu, Zhongyu; Wang, Yitong; Ji, Weijie; Ma, Xiaowei; Gianopoulos, Christopher_G; Calderon, Sebastian; Ma, Timothy; Luo, Lianshun; Mazumder, Abhrojyoti; Kirschbaum, Kristin; et al (February 2025, ACS Nano)
Surface ligand networking promotes intersystem crossing in the Au ₁₈ (SR) ₁₄ nanocluster

https://doi.org/10.1039/D5NH00358J

He, Guiying; Liu, Zhongyu; Wang, Yitong; Sfeir, Matthew Y; Jin, Rongchao (January 2025, Nanoscale Horizons)

The excited state behavior of Au₁₈(SR)₁₄nanoclusters can be controlled by tailoring the surface ligands; specifically, the aromatic ligands’ networking can promote the intersystem crossing in Au₁₈(SR)₁₄compared to the case of non-aromatic ligands.
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Free, publicly-accessible full text available January 1, 2026
Raising Near-Infrared Photoluminescence Quantum Yield of Au ₄₂ Quantum Rod to 50% in Solutions and 75% in Films

https://doi.org/10.1021/jacs.4c11703

Luo, Lianshun; Liu, Zhongyu; Mazumder, Abhrojyoti; Jin, Rongchao (October 2024, Journal of the American Chemical Society)

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