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Abstract NaCl has widely been used as a seeding promoter for chemical vapor deposition of large-scale 2D transition metal dichalcogenides. In this work, we report a study of the influence of NaCl on the growth and optical properties of layered CVD-grown WS₂using steady-state and time-resolved Kerr rotation measurements at room temperature. Strong photoluminescence (PL) signals from single flakes grown with a low NaCl content indicates direct band-gap emission, whereas flakes grown with higher amounts of NaCl exhibit red-shifted, weaker PL. Raman measurements from single flakes also indicate that WS₂grown with higher NaCl amounts result in multilayered structures, while lower NaCl quantities yield monolayer WS₂. Ultrafast carrier decay measurements from single flakes also indicate a NaCl-dependent on the valley exchange interaction component (<10 ps) and slower decay components (>50 ps), attributed to a combination of phenomena, such as the band gap transitioning from direct to indirect and defect-related localized states. Our study provides insight into the influence of seeding promoters in layered CVD-grown WS₂in particular and 2D transition metal dichalcogenides in general.