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We present Barrier-based Simplex (Bb-Simplex), a new, provably correct design for runtime assurance of continuous dynamical systems. Bb-Simplex is centered around the Simplex Control Architecture, which consists of a high-performance advanced controller which is not guaranteed to maintain safety of the plant, a verified-safe baseline controller, and a decision module that switches control of the plant between the two controllers to ensure safety without sacrificing performance. In Bb-Simplex, Barrier certificates are used to prove that the baseline controller ensures safety. Furthermore, Bb-Simplex features a new automated method for deriving, from the barrier certificate, the conditions for switching between the controllers. Our method is based on the Taylor expansion of the barrier certificate and yields computationally inexpensive switching conditions. We consider a significant application of Bb-Simplex to a microgrid featuring an advanced controller in the form of a neural network trained using reinforcement learning. The microgrid is modeled in RTDS, an industry-standard high-fidelity, real-time power systems simulator. Our results demonstrate that Bb-Simplex can automatically derive switching conditions for complex systems, the switching conditions are not overly conservative, and Bb-Simplex ensures safety even in the presence of adversarial attacks on the neural controller.