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This paper is concerned with the numerical solution to the direct and inverse electromagnetic scattering problem for bi-anisotropic periodic structures. The direct problem can be reformulated as an integro-di erential equation. We study the existence and uniqueness of solution to the latter equation and analyze a spectral Galerkin method to solve it. This spectral method is based on a periodization technique which allows us to avoid the evaluation of the quasiperiodic Green's tensor and to use the fast Fourier transform in the numerical implementation of the method. For the inverse problem, we study the orthogonality sampling method to reconstruct the periodic structures from scattering data generated by only two incident fields. The sampling method is fast, simple to implement, regularization free, and very robust against noise in the data. Numerical examples for both direct and inverse problems are presented to examine the efficiency of the numerical solvers.