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Bulk vs. amino acid stable N isotope estimations of metabolic status and contributions of nitrogen fixation to size-fractionated zooplankton biomass in the subtropical N Atlantic
Title: Bulk vs. amino acid stable N isotope estimations of metabolic status and contributions of nitrogen fixation to size-fractionated zooplankton biomass in the subtropical N Atlantic
Ford, Kevin
(, International Mathematics Research Notices)
null
(Ed.)
Abstract We show that for some even $$k\leqslant 3570$$ and all $$k$$ with $442720643463713815200|k$, the equation $$\phi (n)=\phi (n+k)$$ has infinitely many solutions $$n$$, where $$\phi $$ is Euler’s totient function. We also show that for a positive proportion of all $$k$$, the equation $$\sigma (n)=\sigma (n+k)$$ has infinitely many solutions $$n$$. The proofs rely on recent progress on the prime $$k$$-tuples conjecture by Zhang, Maynard, Tao, and PolyMath.
Stenfors, Brock Anton; Ngassa, Felix Nyuangem
(, European Journal of Chemistry)
null
(Ed.)
N-Benzyl-4-methylbenzenesulfonamides were prepared via a two-step synthetic process involving the treatment of 4-methylbenzenesulfonyl chloride with a primary amine to give the corresponding 4-methylbenzenesulfonamide. Benzylation of the sulfonamide affords the substituted N-benzyl-4-methylbenzenesulfonamides. The similarities between the two steps of synthesis lend credence to the development of a one-pot synthesis of substituted N-benzyl-4-methylbenzenesulfonamides from 4-methylbenzenesulfonyl chloride. This method was applied to the synthesis of N-allyl-N-benzyl-4-methylbenzenesulfonamide and characterized through spectroscopic and crystallographic means. The crystal structure of N-allyl-N-benzyl-4-methylbenzenesulfonamide was obtained by single-crystal X-ray diffraction. The crystal structure reveals an orthorhombic Pna21 space group with cell parameters a = 18.6919 (18) Å, b = 10.5612 (10) Å, c = 8.1065 (8) Å, V = 1600.3 (3) Å3 and Z = 4, T = 173.15 K, μ(MoKα) = 0.206 mm-1, Dcalc = 1.251 g/cm3, 14455 reflections measured (4.36° ≤ 2Θ ≤ 54.96°), 3619 unique (Rint = 0.0439, Rsigma = 0.0429) which were used in all calculations. The final R1 was 0.0428 (I > 2σ(I)) and wR2 was 0.1079 (all data). Molecules are linked through C-H···N hydrogen bonds and C-H···π interactions.
Mompeán, Carmen, Bode, Antonio, Gier, Elizabeth, and McCarthy, Matthew D. Bulk vs. amino acid stable N isotope estimations of metabolic status and contributions of nitrogen fixation to size-fractionated zooplankton biomass in the subtropical N Atlantic. Retrieved from https://par.nsf.gov/biblio/10017185. Deep Sea Research Part I: Oceanographic Research Papers . Web. doi:10.1016/j.dsr.2016.05.005.
Mompeán, Carmen, Bode, Antonio, Gier, Elizabeth, & McCarthy, Matthew D. Bulk vs. amino acid stable N isotope estimations of metabolic status and contributions of nitrogen fixation to size-fractionated zooplankton biomass in the subtropical N Atlantic. Deep Sea Research Part I: Oceanographic Research Papers, (). Retrieved from https://par.nsf.gov/biblio/10017185. https://doi.org/10.1016/j.dsr.2016.05.005
Mompeán, Carmen, Bode, Antonio, Gier, Elizabeth, and McCarthy, Matthew D.
"Bulk vs. amino acid stable N isotope estimations of metabolic status and contributions of nitrogen fixation to size-fractionated zooplankton biomass in the subtropical N Atlantic". Deep Sea Research Part I: Oceanographic Research Papers (). Country unknown/Code not available. https://doi.org/10.1016/j.dsr.2016.05.005.https://par.nsf.gov/biblio/10017185.
@article{osti_10017185,
place = {Country unknown/Code not available},
title = {Bulk vs. amino acid stable N isotope estimations of metabolic status and contributions of nitrogen fixation to size-fractionated zooplankton biomass in the subtropical N Atlantic},
url = {https://par.nsf.gov/biblio/10017185},
DOI = {10.1016/j.dsr.2016.05.005},
abstractNote = {},
journal = {Deep Sea Research Part I: Oceanographic Research Papers},
author = {Mompeán, Carmen and Bode, Antonio and Gier, Elizabeth and McCarthy, Matthew D.},
}
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