In the present work we theoretically analyze electroluminescence occurring in a biased single-molecule junction with a chiral bridge imitated by a helical chain. We show that optical transitions between electron states of the chiral linker may result in the emission of circular polarized light whose handedness depends on both direction of propagation and the polarity of the bias voltage provided that the coupling between the bridge sites is sufficiently strong. The mechanism controlling this specific light emission does not depend on the magnetic moments and spin–orbit interactions. It rather relies on the chiral properties of the bridge molecule and on the distribution of the bias voltage between the electrodes in the junction.
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Magnetic light and forbidden photochemistry: the case of singlet oxygen
Most optical processes occurring in nature are based on the well-known selection rules for optical transitions between electronic levels of atoms, molecules, and solids. Since in most situations the magnetic component of light has a negligible contribution, the dipolar electric approximation is generally assumed. However, this traditional understanding is challenged by nanostructured materials, which interact strongly with light and produce very large enhancements of the magnetic field in their surroundings. Here we report on the magnetic response of different metallic nanostructures and their influence on the spectroscopy of molecular oxygen, a paradigmatic example of dipole-forbidden optical transitions in photochemistry.
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- Award ID(s):
- 1710697
- PAR ID:
- 10055607
- Date Published:
- Journal Name:
- Journal of Materials Chemistry C
- Volume:
- 5
- Issue:
- 45
- ISSN:
- 2050-7526
- Page Range / eLocation ID:
- 11824 to 11831
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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