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Title: Unusual rearrangement of an N-heterocyclic carbene via a ring-opening and ring-closing process
The reaction of a pentadentate NHC ligand precursor with Ni(OAc) 2 ·4H 2 O or Pd(OAc) 2 in the presence of a base yields four-coordinate square-planar Ni( ii ) and Pd( ii ) complexes with an unusual ligand generated in situ . A series of experimental studies point to a ring-opening and ring-closing process via novel C–N bond cleavage and formation.  more » « less
Award ID(s):
1633870
NSF-PAR ID:
10062490
Author(s) / Creator(s):
; ; ;
Date Published:
Journal Name:
Chemical Communications
ISSN:
1359-7345
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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