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1. Oxidising agents in sub-arc mantle melts link slab devolatilisation and arc magmas

   https://doi.org/10.1038/s41467-018-05804-2  

   Bénard, Antoine; Klimm, Kevin; Woodland, Alan B.; Arculus, Richard J.; Wilke, Max; Botcharnikov, Roman E.; Shimizu, Nobumichi; Nebel, Oliver; Rivard, Camille; Ionov, Dmitri A. (December 2018, Nature Communications)
2. Quaternary Volcanism in the Cascade Arc

   https://doi.org/10.2138/gselements.18.4.232  

   Kent, Adam J.R. (August 2022, Elements)

   The Cascade arc has produced a remarkable diversity of volcanic rocks over the Quaternary period. The major stratovolcanoes that define the arc front are dominated by eruptions of andesitic and dacitic intermediate magmas, produced largely by fractionation, melting, assimilation, and mixing within the crust. In addition, relative to many other subduction zones, the arc has produced significant mafic volcanism. These more primitive magmas reveal complexity in mantle wedge dynamics, sources, and magma production processes, and suggest that there are significant differences along the arc in the amount of magma that enters the lower Cascade crust from the underlying mantle. 

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3. Late Cretaceous arc flare up and sinistral intra-arc ductile deformation in the southern California batholith, 2022, Late Cretaceous arc flare up and sinistral intra-arc ductile deformation in the southern California batholith

   Schwartz, J.; Lackey, J.S.; Miranda, E.; Klepeis, K.; Mora-Klepeis, G.; Robles, F.; Bixler, J. (October 2022, Geological Society of America Abstracts with Programs)

   We present >90 new igneous and metamorphic zircon and titanite petrochronology ages from the eastern Transverse Ranges of the Southern California Batholith (SCB) to investigate magmatic and tectonic processes in the frontal arc during postulated initiation of Late Cretaceous shallow-slab subduction. Our data cover >4000 km2 in the eastern Transverse Ranges and include data from Mesozoic plutons in the Mt. Pinos, Alamo Mountain, San Gabriel Mountain blocks, and the Eastern Peninsular mylonite zone. Igneous zircon data reveal 4 discrete pulses of magmatism at 258-220 Ma, 160-142 Ma, 120-118 Ma, and 90-66 Ma. The latter pulse involved a widespread magmatic surge in the SCB and coincided with garnet-granulite to upper amphibolite-facies metamorphism and partial melting in the lower crust (Cucamonga terrane, eastern San Gabriel Mountains). In this region, metamorphic zircons in gneisses, migmatites and calc-silicates record high-temperature metamorphism from 91 to 74 Ma at 9–7 kbars and 800–730°C. The Late Cretaceous arc flare-up was temporally and spatially associated with the development of a regionally extensive oblique sinistral-reverse shear system that includes from north to south (present-day) the Tumamait shear zone (Mt. Pinos), the Alamo Mountain-Piru Creek shear zone, the Black Belt shear zone (Cucamonga terrane), and the Eastern Peninsular Ranges shear zone. Syn-kinematic, metamorphic titanite ages in the Tumamait shear zone range from 77–74 Ma at 720–700°C, titanites in the Black Belt mylonite zone give an age of 83 Ma, and those in the eastern Peninsular Ranges mylonite zone give ages of 89–86 Ma at 680–670°C. These data suggest a progressive northward younging of ductile shearing at amphibolite- to upper-amphibolite-facies conditions from 88 to 74 Ma, which overlaps with the timing of the Late Cretaceous arc flare-up event. Collectively, these data indicate that arc magmatism, high-temperature metamorphism, and intra-arc contraction were active in the SCB throughout the Late Cretaceous. These observations appear to contradict existing models for the termination of magmatism and refrigeration of the arc due to underthrusting of the conjugate Shatsky rise starting at ca. 88 Ma. We suggest that shallow-slab subduction likely postdates ca. 74 Ma when high-temperature metamorphism ceased in the SCB. 

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4. Brothers Arc Flux

   https://doi.org/10.14379/iodp.proc.376.2019  

   de Ronde, C.E.J.; Humphris, S.E.; Höfig, T.W. (July 2019, Proceedings of the International Ocean Discovery Program)

   null (Ed.)

   Volcanic arcs are the surface expression of magmatic systems that result from subduction of mostly oceanic lithosphere at convergent plate boundaries. Arcs with a submarine component include intraoceanic arcs and island arcs that span almost 22,000 km on Earth’s surface, and the vast majority of them are located in the Pacific region. Hydrothermal systems hosted by submarine arc volcanoes commonly contain a large component of magmatic fluid. This magmatic-hydrothermal signature, coupled with the shallow water depths of arc volcanoes and their high volatile contents, strongly influences the chemistry of the fluids and resulting mineralization and likely has important consequences for the biota associated with these systems. The high metal content and very acidic fluids in these hydrothermal systems are thought to be important analogs to numerous porphyry copper and epithermal gold deposits mined today on land. During International Ocean Discovery Program (IODP) Expedition 376 (5 May–5 July 2018), a series of five sites was drilled on Brothers volcano in the Kermadec arc. The expedition was designed to provide the missing link (i.e., the third dimension) in our understanding of hydrothermal activity and mineral deposit formation at submarine arc volcanoes and the relationship between the discharge of magmatic fluids and the deep biosphere. Brothers volcano hosts two active and distinct hydrothermal systems: one is seawater influenced and the other is affected by magmatic fluids (largely gases). In total, 222.4 m of volcaniclastics and lavas were recovered from the five sites drilled, which include Sites U1527 and U1530 in the Northwest (NW) Caldera seawater-influenced hydrothermal field; Sites U1528 and U1531 in the magmatic fluid-influenced hydrothermal fields of the Upper and Lower Cones, respectively; and Site U1529, located within an area of low crustal magnetization that marks the West (W) Caldera upflow zone on the caldera floor. Downhole logging and borehole fluid sampling were completed at two sites, and two tests of a prototype turbine-driven coring system (designed by the Center for Deep Earth Exploration [CDEX] at Japan Agency for Marine-Earth Science and Technology [JAMSTEC]) for drilling and coring hard rocks were conducted. Core recovered from all five sites consists of dacitic volcaniclastics and lava flows with only limited chemical variability relative to the overall range in composition of dacites in the Kermadec arc. Pervasive alteration with complex and variable mineral assemblages attest to a highly dynamic hydrothermal system. The upper parts of several drill holes at the NW Caldera hydrothermal field are characterized by secondary mineral assemblages of goethite + opal + zeolites that result from low-temperature (<150°C) reaction of rock with seawater. At depth, NW Caldera Site U1527 exhibits a higher temperature (~250°C) secondary mineral assemblage dominated by chlorite + quartz + illite + pyrite. An older mineral assemblage dominated by diaspore + quartz + pyrophyllite + rutile at the bottom of Hole U1530A is indicative of acidic fluids with temperatures of ~230°–320°C. In contrast, the alteration assemblage at Site U1528 on the Upper Cone is dominated by illite + natroalunite + pyrophyllite + quartz + opal + pyrite, which attests to high-temperature reaction of rocks with acid-sulfate fluids derived from degassed magmatic volatiles and the disproportionation of magmatic SO2. These intensely altered rocks exhibit extreme depletion of major cation oxides, such as MgO, K2O, CaO, MnO, and Na2O. Furthermore, very acidic (as low as pH 1.8), relatively hot (≤236°C) fluids collected at 160, 279, and 313 meters below seafloor in Hole U1528D have chemical compositions indicative of magmatic gas input. In addition, preliminary fluid inclusion data provide evidence for involvement of two distinct fluids: phase-separated (modified) seawater and a ~360°C hypersaline brine, which alters the volcanic rock and potentially transports metals in the system. The material and data recovered during Expedition 376 provide new stratigraphic, lithologic, and geochemical constraints on the development and evolution of Brothers volcano and its hydrothermal systems. Insights into the consequences of the different types of fluid–rock reactions for the microbiological ecosystem elucidated by drilling at Brothers volcano await shore-based studies. 

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5. Prescribed arc graphs

   https://doi.org/10.1007/s10711-025-01000-x  

   Kopreski, Michael C (August 2025, Geometriae Dedicata)