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Title: Silylene-assisted hydride transfer to CO 2 and CS 2 at a [P 2 Si]Ru pincer-type complex
The synthesis and characterization of base-stabilized and base-free pincer-type bis(phosphine)/silylene [P 2 Si]Ru complexes are reported. The base-free complex readily reduces CO 2 and CS 2 via silylene-assisted hydride transfer, affording structurally distinct products with silicon-to-ruthenium formate and dithioformate bridges.  more » « less
Award ID(s):
1552591
PAR ID:
10078662
Author(s) / Creator(s):
; ; ; ;
Date Published:
Journal Name:
Dalton Transactions
Volume:
46
Issue:
43
ISSN:
1477-9226
Page Range / eLocation ID:
14757 to 14761
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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