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Abstract The most reliable single-epoch supermassive black hole mass (MBH) estimates in quasars are obtained by using the velocity widths of low-ionization emission lines, typically the Hβλ4861 line. Unfortunately, this line is redshifted out of the optical band atz≈ 1, leavingMBHestimates to rely on proxy rest-frame ultraviolet (UV) emission lines, such as Civλ1549 or Mgiiλ2800, which contain intrinsic challenges when measuring, resulting in uncertainMBHestimates. In this work, we aim at correctingMBHestimates derived from the Civand Mgiiemission lines based on estimates derived from the Hβemission line. We find that employing the equivalent width of Civin derivingMBHestimates based on Mgiiand Civprovides values that are closest to those obtained from Hβ. We also provide prescriptions to estimateMBHvalues when only Civ, only Mgii, and both Civand Mgiiare measurable. We find that utilizing both emission lines, where available, reduces the scatter of UV-basedMBHestimates by ∼15% when compared to previous studies. Lastly, we discuss the potential of our prescriptions to provide more accurate and precise estimates ofMBHgiven a much larger sample of quasars at 3.20 ≲z≲ 3.50, where both Mgiiand Hβcan be measured in the same near-infrared spectrum.
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Catalyst‐Sidearm‐Induced Stereoselectivity Switching in Polymerization of a Racemic Lactone for Stereocomplexed Crystalline Polymer with a Circular Life Cycle
Abstract Construction of robust, stereocomplexed (sc) crystalline material, based on a recently discovered infinitely recyclable polymer system, requires blending of enantiomeric polymer chains produced from respective enantiopure, fused six‐five bicyclic lactones. Herein, the stereoselective polymerization of the racemic monomer by yttrium catalysts bearing tetradentate ligands is reported, where the tethered donor sidearm switches the heteroselectivity of the catalyst to isoselectivity when it is changed from the β‐OMe to β‐NMe2sidearm. The latter catalyst produces an isotactic stereoblock polymer (Pmup to 0.95) that forms the crystalline sc‐material with aTmof up to 171 °C. This sc‐material can be fully depolymerized back to rac‐monomer in a quantitative yield and purity, thus establishing its circular life cycle.
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- Award ID(s):
- 1664915
- PAR ID:
- 10082264
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Angewandte Chemie International Edition
- Volume:
- 58
- Issue:
- 4
- ISSN:
- 1433-7851
- Page Range / eLocation ID:
- p. 1178-1182
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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