We consider the
B←N coordination supports a [2+2] photodimerization in the solid state. The bond is defined by an orthogonal interaction between stilbazole and a phenylboronic ester to enable a stereocontrolled and rapid photoreaction. The cyclobutane photoproduct affords a novel diboron bis‐tweezer adduct that is used to separate a mixture of benzene and thiophene upon crystallization.
more » « less- Award ID(s):
- 1708673
- PAR ID:
- 10087912
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Angewandte Chemie International Edition
- Volume:
- 58
- Issue:
- 16
- ISSN:
- 1433-7851
- Page Range / eLocation ID:
- p. 5413-5416
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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