Abstract In response to external stimuli, such as heat, light, or magnetic fields, stimuli-responsive soft materials can change their current configuration to a new equilibrium state through non-equilibrium kinetic processes, including reaction, diffusion, and viscoelastic relaxation, which generates novel spatiotemporal shape-morphing behavior. Using a photothermal shape memory polymer (SMP) cantilever beam as a model system, this work analytically, numerically, and experimentally studies its non-equilibrium kinetic processes and spatiotemporal bending under light illumination. We establish a thermomechanical model for SMPs capturing the concurrent non-equilibrium processes of heat transfer and viscoelastic relaxation, which induces inhomogeneous temperature and strain distributions through the thickness of the beam, resulting in its bending and unbending. By varying the key dimensionless parameters, we theoretically and experimentally observe different types of bending dynamics. Moreover, our theory takes into consideration changes in the angles of incidence caused by extensive beam bending, and demonstrates that this effect can dramatically delay the bending due to reduction of the effective light intensity, which is further validated experimentally. This work demonstrates programmable and predictable spatiotemporal morphing of SMPs, and provides design guidelines for SMP morphing structures and robots.
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Applications of Shape Memory Polymers in Kinetic Buildings
Shape memory polymers (SMPs) have attracted significant attention from both industrial and academic researchers, due to their useful and fascinating functionality. One of the most common and studied external stimuli for SMPs is temperature; other stimuli include electric fields, light, magnetic fields, water, and irradiation. Solutions for SMPs have also been extensively studied in the past decade. In this research, we review, consolidate, and report the major efforts and findings documented in the SMP literature, according to different external stimuli. The corresponding mechanisms, constitutive models, and properties (i.e., mechanical, electrical, optical, shape, etc.) of the SMPs in response to different stimulus methods are then reviewed. Next, this research presents and categorizes up-to-date studies on the application of SMPs in dynamic building structures and components. Following this, we discuss the need for studying SMPs in terms of kinetic building applications, especially about building energy saving purposes, and review recent two-way SMPs and their potential for use in such applications. This review covers a number of current advances in SMPs, with a view towards applications in kinetic building engineering.
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- Award ID(s):
- 1635089
- NSF-PAR ID:
- 10093197
- Date Published:
- Journal Name:
- Advances in Materials Science and Engineering
- Volume:
- 2018
- ISSN:
- 1687-8434
- Page Range / eLocation ID:
- 1 to 13
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1155/2018/7453698
