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Title: Externally controlled atom transfer radical polymerization
Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP techniques, e ATRP, photoATRP, and mechanoATRP, are controlled by electrical current, light, and mechanical forces, respectively. Conversely, ARGET and SARA ATRP are controlled by chemical reducing agents. ICAR ATRP is a thermally regulated process through decomposition of a radical initiator. The aim of this review is to highlight the use of external regulations in ATRP and to summarize the state-of-the-art and future perspectives, focusing on mechanistic aspects, synthetic procedures, preparation of polymers with complex architectures and functional materials, and their applications.  more » « less
Award ID(s):
1707490
PAR ID:
10096402
Author(s) / Creator(s):
; ; ;
Date Published:
Journal Name:
Chemical Society Reviews
Volume:
47
Issue:
14
ISSN:
0306-0012
Page Range / eLocation ID:
5457 to 5490
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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