The properties of thin supported polymer films can be dramatically impacted by the substrate upon which it resides. A simple way to alter the properties of the substrate (chemistry, rigidity, dynamics) is by coating it with an immiscible polymer. Here, we describe how ultrathin (ca. 2 nm) hydrophilic polymer layers of poly(acrylic acid) and poly(styrene sulfonate) (PSS) impact the aging behavior and the residual stress in thin films of poly(butylnorbornene‐
The physical aging behavior, time‐dependent densification, of thin polystyrene (PS) films supported on silicon are investigated using ellipsometry for a large range of molecular weights (MWs) from
- Award ID(s):
- 1709132
- NSF-PAR ID:
- 10461487
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Journal of Polymer Science Part B: Polymer Physics
- Volume:
- 57
- Issue:
- 18
- ISSN:
- 0887-6266
- Page Range / eLocation ID:
- p. 1224-1238
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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