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Thermoelectric generators are being used as a successful power sources for space applications since 1960's in radioisotope-thermoelectric generators (RTGs) to supply power to space systems in deep space. RTG’s are capable of directly converting heat energy to uninterrupted electric power with no moving parts involved. The ability of thermoelectric materials to convert heat energy to electrical energy is defined by a dimensionless value known as the thermoelectric figure of merit (ZT) 1. This value quantifies the maximum thermoelectric efficiency of a thermoelectric generator (TEG) and is calculated by ZT= S2σT/κ, where S, σ, T, and κ represent Seebeck coefficient, electrical conductivity, temperature, and thermal conductivity, respectively. Among all of the thermoelectric materials, Bi2Te3 and its alloys have been reported to have high ZT values for low temperature energy harvesting and are highly suitable for powering wearables and self-powering sensors2, 3.
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N-Type Bismuth Telluride Nanocomposite Materials Optimization for Thermoelectric Generators in Wearable Applications
Thermoelectric materials could play a crucial role in the future of wearable electronic devices. They can continuously generate electricity from body heat. For efficient operation in wearable systems, in addition to a high thermoelectric figure of merit, zT, the thermoelectric material must have low thermal conductivity and a high Seebeck coefficient. In this study, we successfully synthesized high-performance nanocomposites of n-type Bi2Te2.7Se0.3, optimized especially for body heat harvesting and power generation applications. Different techniques such as dopant optimization, glass inclusion, microwave radiation in a single mode microwave cavity, and sintering conditions were used to optimize the temperature-dependent thermoelectric properties of Bi2Te2.7Se0.3. The effects of these techniques were studied and compared with each other. A room temperature thermal conductivity as low as 0.65 W/mK and high Seebeck coefficient of −297 μV/K were obtained for a wearable application, while maintaining a high thermoelectric figure of merit, zT, of 0.87 and an average zT of 0.82 over the entire temperature range of 25 °C to 225 °C, which makes the material appropriate for a variety of power generation applications.
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- PAR ID:
- 10106202
- Date Published:
- Journal Name:
- Materials
- Volume:
- 12
- Issue:
- 9
- ISSN:
- 1996-1944
- Page Range / eLocation ID:
- 1529
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3390/ma12091529
