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Atmospheric aerosols significantly offset positive radiative forcing due to their contributions as cloud condensation nuclei (CCN) and ice nucleating particles (INPs). The cloud-aerosol-precipitation interactions in the atmosphere are determined by physical and chemical properties of aerosol particles, which can undergo many cycles of droplet activation and subsequent drying before dry or wet deposition from the atmosphere. Secondary organic aerosol (SOA) is an abundant class of aerosol and has been previously shown to contribute to aerosol formed from cloud processing. Isoprene-derived secondary organic aerosol SOA (iSOA) is a particularly important class of aerosol involved in cloud processing. iSOA has both soluble and insoluble components, but there has been a measurement gap in characterizing the insoluble components, as most analyses have focused on soluble components. These measurements are needed as previous research has suggested that insoluble components could be important with respect to CCN and INP formation. Herein, we analyze the insoluble components of SOA generated from the reactive uptake of IEPOX onto acidic seed particles (ammonium sulfate + sulfuric acid at different ratios for different pH conditions) in an atmospheric chamber. We characterize the size distributions and chemical composition, using NanoParticle Tracking Analysis (NTA), Raman microspectroscopy and atomic force microscopy infrared (AFM-IR) spectroscopy as a function of sulfate aerosol seed pH. These insights may help understand aerosol properties after cloud cycling in the atmosphere.
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An Overview of Dynamic Heterogeneous Oxidations in the Troposphere
Due to the adverse effect of atmospheric aerosols on public health and their ability to affect climate, extensive research has been undertaken in recent decades to understand their sources and sinks, as well as to study their physical and chemical properties. Atmospheric aerosols are important players in the Earth’s radiative budget, affecting incoming and outgoing solar radiation through absorption and scattering by direct and indirect means. While the cooling properties of pure inorganic aerosols are relatively well understood, the impact of organic aerosols on the radiative budget is unclear. Additionally, organic aerosols are transformed through chemical reactions during atmospheric transport. The resulting complex mixture of organic aerosol has variable physical and chemical properties that contribute further to the uncertainty of these species modifying the radiative budget. Correlations between oxidative processing and increased absorptivity, hygroscopicity, and cloud condensation nuclei activity have been observed, but the mechanisms behind these phenomena have remained unexplored. Herein, we review environmentally relevant heterogeneous mechanisms occurring on interfaces that contribute to the processing of aerosols. Recent laboratory studies exploring processes at the aerosol–air interface are highlighted as capable of generating the complexity observed in the environment. Furthermore, a variety of laboratory methods developed specifically to study these processes under environmentally relevant conditions are introduced. Remarkably, the heterogeneous mechanisms presented might neither be feasible in the gas phase nor in the bulk particle phase of aerosols at the fast rates enabled on interfaces. In conclusion, these surface mechanisms are important to better understand how organic aerosols are transformed in the atmosphere affecting the environment.
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- Award ID(s):
- 1255290
- PAR ID:
- 10107213
- Date Published:
- Journal Name:
- Environments
- Volume:
- 5
- Issue:
- 9
- ISSN:
- 2076-3298
- Page Range / eLocation ID:
- 104
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3390/environments5090104
