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1. Facile Light-Induced Transformation of [Ru ^II (bpy) ₂ (bpyNO)] ²⁺ to [Ru ^II (bpy) ₃ ] ²⁺

   https://doi.org/10.1021/acs.inorgchem.0c01446  

   Karbakhsh Ravari, Alireza; Pineda-Galvan, Yuliana; Huynh, Alexander; Ezhov, Roman; Pushkar, Yulia (October 2020, Inorganic Chemistry)

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2. Highly Reactive Co ^III,IV ₂ (μ-O) ₂ Diamond Core Complex That Cleaves C–H Bonds

   https://doi.org/10.1021/jacs.9b09531  

   Li, Yan; Handunneththige, Suhashini; Farquhar, Erik R.; Guo, Yisong; Talipov, Marat R.; Li, Feifei; Wang, Dong (December 2019, Journal of the American Chemical Society)
3. Branching Ratio for O + H ₃ ⁺ Forming OH ⁺ + H ₂ and H ₂ O ⁺ + H

   https://doi.org/10.3847/1538-4357/ac41ce  

   Hillenbrand, Pierre-Michel; Ruette, Nathalie de; Urbain, Xavier; Savin, Daniel W. (March 2022, The Astrophysical Journal)

   Abstract The gas-phase reaction of O + H 3 + has two exothermic product channels: OH + + H 2 and H 2 O + + H. In the present study, we analyze experimental data from a merged-beams measurement to derive thermal rate coefficients resolved by product channel for the temperature range from 10 to 1000 K. Published astrochemical models either ignore the second product channel or apply a temperature-independent branching ratio of 70% versus 30% for the formation of OH + + H 2 versus H 2 O + + H, respectively, which originates from a single experimental data point measured at 295 K. Our results are consistent with this data point, but show a branching ratio that varies with temperature reaching 58% versus 42% at 10 K. We provide recommended rate coefficients for the two product channels for two cases, one where the initial fine-structure population of the O( 3 P J ) reactant is in its J = 2 ground state and the other one where it is in thermal equilibrium. 

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4. Structure, Magnetism, and Multi-electron Reduction Reactivity of the Inverse Sandwich Reduced Arene La ²⁺ Complex [{[C ₅ H ₃ (SiMe ₃ ) ₂ ] ₂ La} ₂ (μ-η ⁶ :η ⁶ -C ₆ H ₆ )] ^1–

   https://doi.org/10.1021/acs.organomet.8b00523  

   Palumbo, Chad T.; Darago, Lucy E.; Dumas, Megan T.; Ziller, Joseph W.; Long, Jeffrey R.; Evans, William J. (September 2018, Organometallics)
5. The Scandium(II) Carbonyl Complex (C ₅ H ₂ ^t Bu ₃ ) ₂ Sc(CO) and Its Isocyanide Analog (C ₅ H ₂ ^t Bu ₃ ) ₂ Sc(CNC ₆ H ₃ Me ₂ -2,6)

   https://doi.org/10.1021/jacs.4c09021  

   Queen, Joshua D; Goudzwaard, Quinn E; Rajabi, Ahmadreza; Ziller, Joseph W; Furche, Filipp; Evans, William J (September 2024, Journal of the American Chemical Society)

   Treatment of the scandium(II) metallocene Cpttt2Sc (Cpttt = C5H2tBu3) with CO or the isocyanide CNXyl (Xyl = C6H3Me2-2,6) yields the carbonyl complex Cpttt2Sc(CO), 1, or the isocyanide complex Cpttt2Sc(CNXyl), 2, which were identified by X-ray crystallography. Isotopic labeling with 13CO shows the CO stretch of 1 at 1875 cm−1 shifts to 1838 cm−1 in 1-13CO. The CN stretch in 2 is shifted to 1939 cm−1 compared to 2118 cm−1 for the free isocyanide. The 80.1 MHz (28.7 G) 45Sc hyperfine coupling in 1 and 74.7 MHz (26.8 G) in 2 are similar to the 82.6 MHz (29.6 G) coupling constant in Cpttt2Sc and indicate that 1 and 2 are Sc(II) complexes. A comprehensive analysis of the electronic structures of 1 and 2 using DFT calculations is reported. 

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