Some of ultrafine-grained (UFG) metals including UFG twinning induced plasticity (TWIP) steels have been found to overcome the paradox of strength and ductility in metals benefiting from their unique deformation modes. Here, this study provides insights into the atomistic process of deformation twin nucleation at Σ3{111} twin boundaries, the dominant type of grain boundary in this UFG high manganese TWIP steel. In response to the applied tensile stresses, grain boundary sliding takes place which changes the structure of coherent Σ3{111} twin boundary from atomistically smooth to partly defective. High resolution transmission electron microscopy demonstrates that the formation of disconnection on Σ3{111} twin boundaries is associated with the motion of Shockley partial dislocations on the boundaries. The twin boundary disconnections act as preferential nucleation sites for deformation twin that is a characteristic difference from the coarse-grained counterpart, and is likely correlated with the lethargy of grain interior dislocation activities, frequently seen in UFG metals. The deformation twin nucleation behavior will be discussed based on in-situ TEM deformation experiments and nanoscale strain distribution analyses results.
A different type of defect, the coherency disclination, is added to disclination types. Disconnections that include disclination content are considered. A criterion is suggested to distinguish disconnections with dislocation content from those with disclination content. Electron microscopy reveals unit disconnections in a low albite grain boundary, defects important in grain boundary sliding. Disconnections of varying step heights are displayed and shown to define both deformed and recovered structures.
more » « less- Award ID(s):
- 1661686
- NSF-PAR ID:
- 10127689
- Publisher / Repository:
- Proceedings of the National Academy of Sciences
- Date Published:
- Journal Name:
- Proceedings of the National Academy of Sciences
- Volume:
- 117
- Issue:
- 1
- ISSN:
- 0027-8424
- Page Range / eLocation ID:
- p. 196-204
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
more » « less
Abstract -
more » « less
Abstract A rigorous methodology is developed for computing elastic fields generated by experimentally observed defect structures within grains in a polycrystal that has undergone tensile extension. An example application is made using a near-field high energy x-ray diffraction microscope measurement of a zirconium sample that underwent
-
more » « less
Grain boundary (GB) structural change is commonly observed during and after stress-driven GB migration in nanocrystalline materials, but its exact atomic scale transformation has not been explored experimentally. Here, using in situ high-resolution transmission electron microscopy combined with molecular dynamics simulations, we observed the dynamic GB structural transformation stemming from reversible facet transformation and GB dissociation during the shear-mediated migration of faceted GBs in gold nanocrystals. A reversible transformation was found to occur between (002)/(111) and Σ11(113) GB facets, accomplished by the coalescence and detachment of
-type GB steps or disconnections that mediated the GB migration. In comparison, the dissociation of (002)/(111) GB into Σ11(113) and Σ3(111) GBs occurred via the reaction of -type steps that involved the emission of partial dislocations. Furthermore, these transformations were loading dependent and could be accommodated by GB junctions. This work provides atomistic insights into the dynamic structural transformation during GB migration. -
more » « less
Abstract We performed deformation and grain growth experiments on natural olivine aggregates with olivine water contents (COH = 600 ± 300 H/106 Si) similar to upper mantle olivine, at 1000–1200°C and 1,400 ± 100 MPa confining pressure. Our experiments differ from published grain growth studies in that most were (1) conducted on natural olivine cores rather than hot‐pressed aggregates and (2) dynamically recrystallized prior to or during grain growth. We combine our results with similar experiments performed at 1200–1300°C and fit the data to a grain growth relationship, yielding a growth exponent (
p ) of 3.2, activation energy (E G V G × 10−6 m3mol−1, and rate constant (k 0) 1.8× 103 mp s−1. OurE G E* = 480 ± 40 kJ mol−1). Grain size in strain rate‐stepping samples adjusted to the olivine piezometer within 1.3–7.9% strain. The active grain boundary migration processes during deformation and dynamic recrystallization affect the kinetics of postdeformation grain growth, as grain boundary migration driven by strain energy density (ρ GBM) may delay the onset of grain growth driven by interfacial energy (γGBM). We compared our postdeformation grain growth rates with data from previously published hydrostatic annealing experiments on synthetic olivine. At geologic timescales, the growth rates are much slower than predicted by the existing wet olivine grain growth law. -
null (Ed.)We examine the regime between crystalline and amorphous packings of anisotropic objects on surfaces of different genus by continuously varying their size distribution or shape from monodispersed spheres to bidispersed mixtures or monodispersed ellipsoidal particles; we also consider an anisotropic variant of the Thomson problem with a mixture of charges. With increasing anisotropy, we first observe the disruption of translational order with an intermediate orientationally ordered hexatic phase as proposed by Nelson, Rubinstein and Spaepen, and then a transition to amorphous state. By analyzing the structure of the disclination motifs induced, we show that the hexatic-amorphous transition is caused by the growth and connection of disclination grain boundaries, suggesting this transition lies in the percolation universality class in the scenarios considered.more » « less
