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Abstract Great opportunities emerge not only in the generation of anisotropic plasmonic nanostructures but also in controlling their orientation relative to incident light. Herein, a stepwise seeded growth method is reported for the synthesis of rod‐shaped plasmon nanostructures which are vertically self‐aligned with respect to the surface of colloidal substrates. Anisotropic growth of metal nanostructure is achieved by depositing metal seeds onto the surface of colloidal substrates and then selectively passivating the seed surface to induce symmetry breaking in the subsequent seed‐mediated growth process. The versatility of this method is demonstrated by producing nanoparticle dimers and linear trimers of Au, Au–Ag, Au–Pd, and Au–Cu2O. Further, this unique method enables the automatic vertical alignment of the resulting plasmonic nanostructures to the surface of the colloidal substrate, thereby making it possible to design magnetic/plasmonic nanocomposites that allow the dynamic tuning of the plasmon excitation by controlling their orientation using an external magnetic field. The controlled anisotropic growth of colloidal plasmonic nanostructures and their dynamic modulation of plasmon excitation further allow them to be conveniently fixed in a thin polymer film with a well‐controlled orientation to display polarization‐dependent patterns that may find important applications in information encryption.
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Dynamic Tuning of Optical Transmittance of 1D Colloidal Assemblies of Magnetic Nanostructures
Smart materials with switchable optical properties may find interesting applications in designing advanced intelligent systems. Herein, the dynamic tuning of optical transmission is reported by controlling the orientation of 1D colloidal assemblies of magnetic nanostructures. Colloidal magnetic nanostructures of Fe3O4, including nanospheres, nanorods, and nanodiscs, are assembled into 1D chains under external magnetic fields. Magnetic tuning of the orientation of the nanochains results in a pronounced contrast in optical transmittance, which is strongly dependent on the size and shape of the primary nanostructures. Contrary to the intuitive expectation, the 1D chains of the nanospheres and nanorods exhibit lower transmittance when they are oriented parallel rather than perpendicular to the incident light, whereas the nanodisc counterpart responds oppositely due to the unique “edge‐to‐edge” assembly mode of the nanodiscs. The dynamic tuning of the optical transmittance through magnetic means is believed to have broad applications in the design of novel switchable optical devices. As an example, the incorporation of orientation‐dependent optical properties of 1D chains into the construction of intelligent polymer films with their transparency sensitive to rotation and bending is demonstrated.
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- Award ID(s):
- 1810485
- PAR ID:
- 10127701
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Intelligent Systems
- Volume:
- 1
- Issue:
- 8
- ISSN:
- 2640-4567
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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