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1. Diisobutylammonium triphenyl(2-thiolatoacetato-κ ² O , S )stannate(IV)

   https://doi.org/10.1107/S2414314624007429  

   Song, Xueqing; Yeibyo, Woldegebriel; Li, William; Pike, Robert D (August 2024, IUCrData)

   Crystals of the title salt, (C₈H₂₀N)[Sn(C₆H₅)₃(C₂H₂O₂S)], comprise diisobutylammonium cations and mercaptoacetatotriphenylstannate(IV) anions. The bidentate binding mode of the mercaptoacetate ligand gives rise to a five-coordinated, ionic triphenyltin complex with a distortedcis-trigonal–bipyramidal geometry around the tin atom. In the crystal, charge-assisted ammonium-N—H...O(carboxylate) hydrogen-bonding connects two cations and two anions into a four-ion aggregate. Two positions were resolved for one of the phenyl rings with the major component having a site occupancy factor of 0.60 (3). 

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2. 5-([( Z )-Methoxyimino]{2-[(2-methylphenoxy)methyl]phenyl}methyl)-1,3,4-oxadiazole-2(3 H )-thione dimethyl sulfoxide monosolvate

   https://doi.org/10.1107/S2414314623002377  

   Shripanavar, Chetan Shrimandhar; Balerao, Rishik; Butcher, Ray J. (March 2023, IUCrData)

   The title compound, C 18 H 17 N 3 O 3 S·C 2 H 6 OS, crystallizes in the monoclinic space group P 2 1 /c . In the crystal, C 1 1 (9) chains of C—H...O interactions are formed, propogating in the c -axis direction. The N—H hydrogen atom forms a strong hydrogen bond with the oxygen atom of a DMSO solvate molecule. 

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3. Phenanthroline-Catalyzed Stereoselective Formation of α-1,2- cis 2-Deoxy-2-Fluoro Glycosides

   https://doi.org/10.1021/acscatal.0c04381  

   DeMent, Paul M.; Liu, Chenlu; Wakpal, Joseph; Schaugaard, Richard N.; Schlegel, H. Bernhard; Nguyen, Hien M. (February 2021, ACS Catalysis)

   null (Ed.)
4. Self-assembly snapshots of a 2 × 2 copper(I) grid

   https://doi.org/10.1080/10610278.2013.872780  

   Manck, Lauren E.; Benson, Christopher R.; Share, Andrew I.; Park, Hyunsoo; Vander Griend, Douglas A.; Flood, Amar H. (March 2014, Supramolecular Chemistry)
5. Dichlorido{(E)-N,N-dimethyl-2-[phenyl(pyridin-2-yl)methylidene]hydrazine-1-carbothioamide}cadmium(II)

   https://doi.org/10.1107/S241431462500464X  

   Parry, Christian S; Kwabi-Addo, Bernard; Ramadhar, Timothy R; Butcher, Raymond J (May 2025, IUCrData)

   The structure of the title compound, [CdCl₂(C₁₅H₁₆N₄S)], at 100 K has monoclinic (P2₁/c) symmetry. The compound has a layer structure and is a 1:1 complex of the organic ligand and cadmium chloride. The ligand, 3,3-dimethyl-1-[(E)-[phenyl(pyridine-2-yl)methylidene]amino]thiourea (L, Bp44mT), is of interest with respect to anticancer activity, antiviral properties and potential use in conditions of iron overload, from hemochromatosis or from multiple transfusions in hematological disorders such as sickle cell disease or beta thalassemia. This study is aimed at uncovering the basis of selectivity of the ligand as a chelator and for lead optimization. We also examine the ligand's potential use in treating heavy metal poisoning from cadmium, arsenic, lead or mercury, and for environmental remediation. The crystal structure exhibits no intermolecular or intramolecular hydrogen bonding with the supramolecular features being driven by hydrophobic, π–π and long-range dispersion forces. 

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