Crystals of the title salt, (C8H20N)[Sn(C6H5)3(C2H2O2S)], comprise diisobutylammonium cations and mercaptoacetatotriphenylstannate(IV) anions. The bidentate binding mode of the mercaptoacetate ligand gives rise to a five-coordinated, ionic triphenyltin complex with a distortedcis-trigonal–bipyramidal geometry around the tin atom. In the crystal, charge-assisted ammonium-N—H...O(carboxylate) hydrogen-bonding connects two cations and two anions into a four-ion aggregate. Two positions were resolved for one of the phenyl rings with the major component having a site occupancy factor of 0.60 (3). 
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                            Correction to Synthesis of N -Alkenyl 2-Pyridonyl Ethers via a Au(I)-Catalyzed Rearrangement of 2-Propargyloxypyridines
                        
                    - Award ID(s):
- 1266314
- PAR ID:
- 10143258
- Date Published:
- Journal Name:
- The Journal of Organic Chemistry
- Volume:
- 85
- Issue:
- 5
- ISSN:
- 0022-3263
- Page Range / eLocation ID:
- 3990 to 3991
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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