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1. Wire like diplatinum, triplatinum, and tetraplatinum complexes featuring X[PtCCCCCCCC] _m PtX segments; iterative syntheses and functionalization for measurements of single molecule properties

   https://doi.org/10.1039/C9DT00870E  

   Zheng, Qinglin; Schneider, Jakob F.; Amini, Hashem; Hampel, Frank; Gladysz, John A. (April 2019, Dalton Transactions)

   Reaction of ( p -tol 3 P) 2 PtCl 2 and Me 3 Sn(CC) 2 SiMe 3 (1 : 1/THF/reflux) gives monosubstituted trans -Cl( p -tol 3 P) 2 Pt(CC) 2 SiMe 3 (63%), which with wet n -Bu 4 N + F − yields trans -Cl( p -tol 3 P) 2 Pt(CC) 2 H ( 2 , 96%). Hay oxidative homocoupling (O 2 /CuCl/TMEDA) gives all- trans -Cl( p -tol 3 P) 2 Pt(CC) 4 Pt(P p -tol 3 ) 2 Cl ( 3 , 68%). Reaction of 3 and Me 3 Sn(CC) 2 SiMe 3 (1 : 1/rt) affords monosubstituted all- trans -Cl( p -tol 3 P) 2 Pt(CC) 4 Pt(P p -tol 3 ) 2 (CC) 2 SiMe 3 (46%), which is converted by a similar desilylation/homocoupling sequence to all- trans -Cl[( p -tol 3 P) 2 Pt(CC) 4 ] 3 Pt(P p -tol 3 ) 2 Cl ( 7 ; 79%). Reaction of ( p -tol 3 P) 2 PtCl 2 and excess H(CC) 2 SiMe 3 (HNEt 2 /cat. CuI) gives trans -Me 3 Si(CC) 2 Pt(P p -tol 3 ) 2 (CC) 2 SiMe 3 (78%), which with wet n -Bu 4 N + F − affords trans -H(CC) 2 Pt(P p -tol 3 ) 2 (CC) 2 H (96%). Hay oxidative cross coupling with 2 (1 : 4) gives all- trans -Cl[( p -tol 3 P) 2 Pt(CC) 4 ] 2 Pt(P p -tol 3 ) 2 Cl ( 10 , 36%) along with homocoupling product 3 (33%). Reaction of 3 and Me 3 Sn(CC) 2 SiMe 3 (1 : 2/rt) yields all- trans -Me 3 Si(CC) 2 ( p -tol 3 P) 2 Pt(CC) 4 Pt(P p -tol 3 ) 2 (CC) 2 SiMe 3 ( 17 , 77%), which with wet n -Bu 4 N + F − gives all- trans -H(CC) 2 ( p -tol 3 P) 2 Pt(CC) 4 Pt(P p -tol 3 ) 2 (CC) 2 H (96%). Reaction of 3 and excess Me 3 P gives all- trans -Cl(Me 3 P) 2 Pt(CC) 4 Pt(PMe 3 ) 2 Cl ( 4 , 86%). A model reaction of trans -( p -tol)( p -tol 3 P) 2 PtCl and KSAc yields trans -( p -tol)( p -tol 3 P) 2 PtSAc ( 12 , 75%). Similar reactions of 3 , 7 , 10 , and 4 give all- trans -AcS[(R 3 P) 2 Pt(CC) 4 ] n Pt(PR 3 ) 2 SAc (76–91%). The crystal structures of 3 , 17 , and 12 are determined. The first exhibits a chlorine–chlorine distance of 17.42 Å; those in 10 and 7 are estimated as 30.3 Å and 43.1 Å. 

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2. Synthesis and Crystal Structure of the Conjugated Tetrayne (5-C5Me5)Re(NO)(PPh3)-(CCCCCCCCSiMe3): Application of the Cadiot-Chodkiewicz Coupling Reaction to the Chain Extension of Metal-Capped sp-Carbon Wires

   Bartik, B.; Dembinski, R.; Bartik, T.; Arif, A. M.; Gladysz, J. A. (January 1997, New journal of chemistry)
3. Photoredox catalyzed C(sp3) C(sp) coupling of dihydropyridines and alkynylbenziodoxolones

   https://doi.org/10.1016/j.tetlet.2019.151230  

   Liang, Shengzong; Angnes, Ricardo A.; Potnis, Chinmay S.; Hammond, Gerald B. (November 2019, Tetrahedron Letters)
4. SÍGAME Simulations of the [{ m{C}},{ m{II}}], [{ m{O}},{ m{I}}], and [{ m{O}},{ m{III}}] Line Emission from Star-forming Galaxies at zsimeq 6

   Olsen, Karen; Greve, Thomas R.; Narayanan, Desika; Thompson, Robert; Davé, Romeel; Niebla Rios, Luis; Stawinski, Stephanie (January 2017, Astrophysical journal)

   Of the almost 40 star-forming galaxies at z≳ 5 (not counting quasi-stellar objects) observed in [{{C}} {{II}}] to date, nearly half are either very faint in [{{C}} {{II}}] or not detected at all, and fall well below expectations based on locally derived relations between star formation rate and [{{C}} {{II}}] luminosity. This has raised questions as to how reliable [{{C}} {{II}}] is as a tracer of star formation activity at these epochs and how factors such as metallicity might affect the [{{C}} {{II}}] emission. Combining cosmological zoom simulations of galaxies with SÍGAME (SImulator of GAlaxy Millimeter/submillimeter Emission), we modeled the multiphased interstellar medium (ISM) and its emission in [{{C}} {{II}}], as well as in [O I] and [O III], from 30 main-sequence galaxies at z≃ 6 with star formation rates ˜3-23 {M}⊙ {yr}}-1, stellar masses ˜ (0.7{--}8)× {10}9 {M}⊙ , and metallicities ˜ (0.1{--}0.4)× {Z}⊙ . The simulations are able to reproduce the aforementioned [{{C}} {{II}}] faintness of some normal star-forming galaxy sources at z≥slant 5. In terms of [O I] and [O III], very few observations are available at z≳ 5, but our simulations match two of the three existing z≳ 5 detections of [O III] and are furthermore roughly consistent with the [O I] and [O III] luminosity relations with star formation rate observed for local starburst galaxies. We find that the [{{C}} {{II}}] emission is dominated by the diffuse ionized gas phase and molecular clouds, which on average contribute ˜66% and ˜27%, respectively. The molecular gas, which constitutes only ˜ 10 % of the total gas mass, is thus a more efficient emitter of [{{C}} {{II}}] than the ionized gas, which makes up ˜85% of the total gas mass. A principal component analysis shows that the [{{C}} {{II}}] luminosity correlates with the star formation activity of a galaxy as well as its average metallicity. The low metallicities of our simulations together with their low molecular gas mass fractions can account for their [{{C}} {{II}}] faintness, and we suggest that these factors may also be responsible for the [{{C}} {{II}}]-faint normal galaxies observed at these early epochs. 

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5. Electroreductive C–C Coupling of Furfural and Benzaldehyde on Cu and Pb Surfaces

   https://doi.org/10.1021/acscatal.0c03110  

   Anibal, Jacob; Xu, Bingjun (October 2020, ACS Catalysis)