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1. Crystallographic characterization of rare-earth cyanotriphenylborate complexes and the cyanoborates [NCBPh ₃ ] ¹⁻ , [NCBPh ₂ Me] ¹⁻ , and [NCBPh ₂ (μ-O)BPh ₂ ] ¹⁻

   https://doi.org/10.1107/S2056989021006861  

   Dumas, Megan T.; White, Jessica R.; Ziller, Joseph W.; Evans, William J. (August 2021, Acta Crystallographica Section E Crystallographic Communications)

   The investigation of the coordination chemistry of rare-earth metal complexes with cyanide ligands led to the isolation and crystallographic characterization of the Ln III cyanotriphenylborate complexes dichlorido(cyanotriphenylborato-κ N )tetrakis(tetrahydrofuran-κ O )lanthanide(III), [ Ln Cl 2 (C 19 H 15 BN)(C 4 H 8 O) 4 ] [lanthanide ( Ln ) = dysprosium (Dy) and yttrium Y)] from reactions of LnCl 3 , KCN, and NaBPh 4 . Attempts to independently synthesize the tetraethylammonium salt of (NCBPh 3 ) − from BPh 3 and [NEt 4 ][CN] in THF yielded crystals of the phenyl-substituted cyclic borate, tetraethylazanium 2,2,4,6-tetraphenyl-1,3,5,2λ 4 ,4,6-trioxatriborinan-2-ide, C 8 H 20 N + ·C 24 H 20 B 3 O 3 − or [NEt 4 ][B 3 (μ-O) 3 (C 6 H 5 ) 4 ]. The mechanochemical reaction of BPh 3 and [NEt 4 ][CN] without solvent produced crystals of tetraethylazanium cyanodiphenyl-λ 4 -boranyl diphenylborinate, C 8 H 20 N + ·C 25 H 20 B 2 NO − or [NEt 4 ][NCBPh 2 (μ-O)BPh 2 ]. Reaction of BPh 3 and KCN in THF in the presence of 2.2.2-cryptand (crypt) led to a crystal of bis[(2.2.2-cryptand)potassium] 2,2,4,6-tetraphenyl-1,3,5,2λ 4 ,4,6-trioxatriborinan-2-ide cyanomethyldiphenylborate tetrahydrofuran disolvate, 2C 18 H 36 KN 2 O 6 + ·C 24 H 20 B 3 O 3 − ·C 14 H 13 BN − ·2C 4 H 8 O or [K(crypt)] 2 [B 3 (μ-O) 3 (C 6 H 5 ) 4 ][NCBPh 2 Me]·2THF. The [NCBPh 2 (μ-O)BPh 2 ] 1− and (NCBPh 2 Me) 1− anions have not been structurally characterized previously. The structure of 1-Y was refined as a two-component twin with occupancy factors 0.513 (1) and 0.487 (1). In 4 , one solvent molecule was disordered and included using multiple components with partial site-occupancy factors. 

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2. Gas-Phase Preparation of 1-Germavinylidene (H ₂ CGe; X ¹ A ₁ ), the Isovalent Counterpart of Vinylidene (H ₂ CC; X ¹ A ₁ ), via Non-adiabatic Dynamics through the Elementary Reaction of Ground State Atomic Carbon (C; ³ P) with Germane (GeH ₄ ; X ¹ A ₁ )

   https://doi.org/10.1021/acs.jpclett.2c03749  

   Yang, Zhenghai; Sun, Bing-Jian; He, Chao; Li, Jin-Qi; Chang, Agnes H.; Kaiser, Ralf I. (January 2023, The Journal of Physical Chemistry Letters)
3. The Role of Tunneling in the Spectra of H ₅ ⁺ and D ₅ ⁺ up to 7300 cm ^-1

   https://doi.org/10.1021/acs.jpca.0c02299  

   Boyer, Mark A.; Chiu, Chloe S.; McDonald, David C.; Wagner, J. Philipp; Colley, Jason E.; Orr, Dylan S.; Duncan, Michael A.; McCoy, Anne B. (May 2020, The Journal of Physical Chemistry A)

   The spectra for H5+ and D5+ are extended to cover the region between 4830 and 7300 cm−1. These spectra are obtained using mass-selected photodissociation spectroscopy. To understand the nature of the states that are accessed by the transitions in this and prior studies, we develop a four-dimensional model Hamiltonian. This Hamiltonian is expressed in terms of the two outer H2 stretches, the displacement of the shared proton from the center of mass of these two H2 groups, and the distance between the H2 groups. This choice is motivated by the large oscillator strength associated with the shared proton stretch and the fact that the spectral regions that have been probed correspond to zero, one, and two quanta of excitation in the H2 stretches. This model is analyzed using an adiabatic separation of the H2 stretches from the other two vibrations and includes the non-adiabatic couplings between H2 stretch states with the same number of quanta of excitation in the H2 stretches. Based on the analysis of the energies and wave functions obtained from this model, we find that when there are one or more quanta of excitation in the H2 stretches the states come in pairs that reflect tunneling doublets. The states accessed by the transitions in the spectrum with the largest intensity are assigned to the members of the doublets with requisite symmetry that are localized on the lowest-energy adiabat for a given level of H2 excitation. 

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4. Electrochemical Oxidation of [1-X-12-I-CB ₁₁ Me ₁₀ ^– ] Anions: Formation of Borenium Ylides [12-Dehydro-1-X-CB ₁₁ Me ₁₀ ] and Iodonium Ylide Anions [{12-(1-X-CB ₁₁ Me ₁₀ ^– )} ₂ I ⁺ ]

   https://doi.org/10.1021/acs.inorgchem.6b02128  

   Wahab, Abdul; Kaleta, Jiří; Wen, Jin; Valášek, Michal; Polášek, Miroslav; Michl, Josef; Ludvík, Jiří (December 2016, Inorganic Chemistry)
5. Probing the electronic structure of the CoB ₁₆ ⁻ drum complex: Unusual oxidation state of Co ⁻¹

   https://doi.org/10.1063/1674-0068/cjcp1903050  

   Li, Wan-Lu; Chen, Teng-Teng; Jiang, Zhi-Yu; Chen, Wei-Jia; Hu, Han-Shi; Wang, Lai-Sheng; Li, Jun (April 2019, Chinese Journal of Chemical Physics)