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Title: Regulated lithium ionic flux through well-aligned channels for lithium dendrite inhibition in solid-state batteries
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Energy Storage Materials
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National Science Foundation
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  1. The shuttling of polysulfides and uncontrollable growth of lithium dendrites remain the most critical obstacles deteriorating the performance and safety of lithium–sulfur batteries. The separator plays a key role in molecule diffusion and ion transport kinetics; thus, endowing the separator with functions to address the two abovementioned issues is an urgent need. Herein, a protein-based, low-resistance Janus nanofabric is designed and fabricated for simultaneously trapping polysulfides and stabilizing lithium metal. The Janus nanofabric is achieved via combining two functional nanofabric layers, a gelatin-coated conductive nanofabric (G@CNF) as a polysulfide-blocking layer and a gelatin nanofabric (G-nanofabric) as an ion-regulating layer, into a heterostructure. The gelatin coating of G@CNF effectively enhances the polysulfide-trapping ability owing to strong gelatin–polysulfide interactions. The G-nanofabric with exceptional wettability, high ionic conductivity (4.9 × 10 −3 S cm −1 ) and a high lithium-ion transference number (0.73) helps stabilize ion deposition and thus suppresses the growth of lithium dendrites. As a result, a Li/Li symmetric cell with the G-nanofabric delivers ultra-long cycle life over 1000 h with very stable performance. Benefiting from the synergistic effect of the two functional layers of the Janus nanofabric, the resulting Li–S batteries demonstrate excellent capacity, rate performance and cycling stability (more »e.g. initial discharge capacity of 890 mA h g −1 with a decay rate of 0.117% up to 300 cycles at 0.5 A g −1 ).« less