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Title: Electron injection into titanium dioxide by panchromatic dirhodium photosensitizers with low energy red light
Two new Rh 2 ( ii , ii ) dyes were synthesized and anchored to TiO 2 for charge injection upon irradiation. The 1 ML-LCT (metal/ligand-to-ligand charge transfer) excited state is populated upon excitation, which decays to the corresponding 3 ML-LCT state. Ultrafast electron injection into TiO 2 from the Rh 2 ( ii , ii ) dyes was achieved with low energy, red light excitation.  more » « less
Award ID(s):
1800395
PAR ID:
10179467
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Chemical Communications
Volume:
55
Issue:
70
ISSN:
1359-7345
Page Range / eLocation ID:
10428 to 10431
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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