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A series of Ru( ii )-terpyridine complexes containing electron-donating bidentate ligands are able to effectively photodissociate nitrile ligands using red light. A spectroscopic investigation of these complexes reveal that they follow anti-energy gap law behavior, providing further evidence that population of 3 LF excited states is not necessary for photoinduced nitrile dissociation.more » « less
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Two new Rh 2 ( ii , ii ) dyes were synthesized and anchored to TiO 2 for charge injection upon irradiation. The 1 ML-LCT (metal/ligand-to-ligand charge transfer) excited state is populated upon excitation, which decays to the corresponding 3 ML-LCT state. Ultrafast electron injection into TiO 2 from the Rh 2 ( ii , ii ) dyes was achieved with low energy, red light excitation.more » « less
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