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1. Structure and Properties of Portland-Limestone Cements Synthesized with Biologically Architected Calcium Carbonate

   Murphy, Madalyn C.; Beatty, Daniell N.; Srubar III, WV. (June 2023, Proceedings of ICBBM 2023: Biobased Building Materials)

   Amziane, S; Merta, I; Page, J. (Ed.)

   Portland cement is one of the most used materials on earth. Its annual production is responsible for approximately 7% of global carbon dioxide (CO2) emissions. These emissions are primarily associated with (1) the burning of fossil fuels to heat cement kilns and (2) the release of CO2 during limestone calcination. One proposed strategy for CO2 reduction includes the use of functional limestone fillers, which reduce the amount of portland cement in concrete without compromising strength. This study investigated the effect of using renewable, CO2-storing, biogenic CaCO3 produced by E. huxleyi as limestone filler in portland limestone cements (PLCs). Biogenic CaCO3 was used to synthesize PLCs with 0, 5, 15, and 35% limestone replacement of portland cement. The results substantiate that the particle sizes of the biogenic CaCO3 were significantly smaller and the surface areas significantly larger than that of reagent grade CaCO3. X-ray diffraction indicated no differences in mineralogy between reagent-grade and biogenic CaCO3. The use of biogenic CaCO3 as a limestone filler led to (i) increased water demand at the higher replacements, which was countered by using a superplasticizer, and (ii) enhanced nucleation during cement hydration, as measured by isothermal conduction calorimetry. The 7-day compressive strengths of the PLC pastes were measured using mechanical testing. Enhanced nucleation effects were observed for PLC samples containing biogenic CaCO3. 7-day compressive strength of the PLCs produced using biogenic CaCO3 were also enhanced compared to PLCs produced using reagent-grade CaCO3 due to the nucleation effect. This study illustrates an opportunity for using CO2-storing, biogenic CaCO3 to enhance mechanical properties and CO2 storage in PLCs containing biologically architected CaCO3. 

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2. On the Bonding Characteristics of Clays and Biopolymers for Sustainable Earthen Construction

   Mikofsky, R.A.; Armistead, S.J.; Srubar, W.V. (June 2023, International Conference on Bio-Based Building Materials)

   Amziane, S.; Merta, I.; Page, J. (Ed.)

   Sustainable earthen building materials provide a pathway to mitigating the environmental impacts of the modern construction sector. While the application of these materials has been limited due to the inherent heterogeneity, erosivity, and weak mechanical properties of soil, the physical and thermal properties can be improved through the addition of ubiquitous, non-toxic, sustainable biopolymers. Yet, the fundamental understanding of the physiochemical bonding mechanisms between clays and biopolymers in this system is limited. In this work, a ‘micro to macro’ methodological approach was applied to investigate the bonding characteristics of common clays and clay-stabilizing biopolymers. At the micro-scale, fundamental interactions of clays (i.e., kaolinite, bentonite) with biopolymer additives (i.e., xanthan gum, guar gum, sodium alginate, microcrystalline cellulose) were assessed through mineral binding characterization techniques, including Fourier-transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). The findings were used to interpret unconfined compressive strength (UCS) tests results for macro-scale soil-biopolymer composites samples (1% biopolymer by soil mass). The results from this study illustrate the utility of understanding the mechanisms of clay-biopolymer interactions for improving the design of strong and durable earthen materials and structures. 

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3. Microbial Catalysis for CO ₂ Sequestration: A Geobiological Approach

   https://doi.org/10.1101/cshperspect.a041673  

   Van_Den_Berghe, Martin; Walworth, Nathan G; Dalvie, Neil C; Dupont, Chris L; Springer, Michael; Andrews, M Grace; Romaniello, Stephen J; Hutchins, David A; Montserrat, Francesc; Silver, Pamela A; et al (May 2024, Cold Spring Harbor Perspectives in Biology)

   One of the greatest threats facing the planet is the continued increase in excess greenhouse gasses, with CO2 being the primary driver due to its rapid increase in only a century. Excess CO2 is exacerbating known climate tipping points that will have cascading local and global effects including loss of biodiversity, global warming, and climate migration. However, global reduction of CO2 emissions is not enough. Carbon dioxide removal (CDR) will also be needed to avoid the catastrophic effects of global warming. Although the drawdown and storage of CO2 occur naturally via the coupling of the silicate and carbonate cycles, they operate over geological timescales (thousands of years). Here, we suggest that microbes can be used to accelerate this process, perhaps by orders of magnitude, while simultaneously producing potentially valuable by-products. This could provide both a sustainable pathway for global drawdown of CO2 and an environmentally benign biosynthesis of materials. We discuss several different approaches, all of which involve enhancing the rate of silicate weathering. We use the silicate mineral olivine as a case study because of its favorable weathering properties, global abundance, and growing interest in CDR applications. Extensive research is needed to determine both the upper limit of the rate of silicate dissolution and its potential to economically scale to draw down significant amounts (Mt/Gt) of CO2. Other industrial processes have successfully cultivated microbial consortia to provide valuable services at scale (e.g., wastewater treatment, anaerobic digestion, fermentation), and we argue that similar economies of scale could be achieved from this research. 

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4. Enhanced Dielectric Permittivity of Optimized Surface Modified of Barium Titanate Nanocomposites

   https://doi.org/10.3390/polym12040827  

   Sundar, Udhay; Lao, Zichen; Cook-Chennault, Kimberly (April 2020, Polymers)

   null (Ed.)

   High permittivity polymer-ceramic nanocomposite dielectric films take advantage of the ease of flexibility in processing of polymers and the functionality of electroactive ceramic fillers. Hence, films like these may be applied to embedded energy storage devices for printed circuit electrical boards. However, the incompatibility of the hydrophilic ceramic filler and hydrophobic epoxy limit the filler concentration and therefore, dielectric permittivity of these materials. Traditionally, surfactants and core-shell processing of ceramic fillers are used to achieve electrostatic and steric stabilization for adequate ceramic particle distribution but, questions regarding these processes still remain. The purpose of this work is to understand the role of surfactant concentration ceramic particle surface morphology, and composite dielectric permittivity and conductivity. A comprehensive study of barium titanate-based epoxy nanocomposites was performed. Ethanol and 3-glycidyloxypropyltrimethoxysilan surface treatments were performed, where the best reduction in particle agglomeration, highest value of permittivity and the lowest value of loss were observed. The results demonstrate that optimization of coupling agent may lead to superior permittivity values and diminished losses that are ~2–3 times that of composites with non-optimized and traditional surfactant treatments. 

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5. Clay calcination technology: state-of-the-art review by the RILEM TC 282-CCL

   https://doi.org/10.1617/s11527-021-01807-6  

   Hanein, Theodore; Thienel, Karl-Christian; Zunino, Franco; Marsh, Alastair T.; Maier, Matthias; Wang, Bin; Canut, Mariana; Juenger, Maria C.; Ben Haha, Mohsen; Avet, François; et al (January 2022, Materials and Structures)

   Abstract The use of calcined clays as supplementary cementitious materials provides the opportunity to significantly reduce the cement industry’s carbon burden; however, use at a global scale requires a deep understanding of the extraction and processing of the clays to be used, which will uncover routes to optimise their reactivity. This will enable increased usage of calcined clays as cement replacements, further improving the sustainability of concretes produced with them. Existing technologies can be adopted to produce calcined clays at an industrial scale in many regions around the world. This paper, produced by RILEM TC 282-CCL on calcined clays as supplementary cementitious materials (working group 2), focuses on the production of calcined clays, presents an overview of clay mining, and assesses the current state of the art in clay calcination technology, covering the most relevant aspects from the clay deposit to the factory gate. The energetics and associated carbon footprint of the calcination process are also discussed, and an outlook on clay calcination is presented, discussing the technological advancements required to fulfil future global demand for this material in sustainable infrastructure development. 

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