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1. Freshwater Salinization Syndrome Alters Retention and Release of ‘Chemical Cocktails’ along Flowpaths:  from Stormwater Management to Urban Streams

   https://doi.org/10.1086/721469  

   Kaushal, Sujay; Reimer, Jenna E.; Mayer, Paul M.; Shatkay, Ruth R.; Maas, Carly; Nguyen, William D.; Boger, Walter L.; Yaculak, Alexis M.; Doody, Thomas R.; Pennino, Michael; et al (June 2022, Freshwater Science)

   Freshwater salinization syndrome (FSS) refers to the suite of interactive effects of salt ions on degradation of physical, biological,and social systems. Best management practices (BMPs), which are methods to effectively reduce runoff and nonpoint source pollution (stormwater, nutrients, sediments), do not typically consider management of salt pollution. We investigate impacts of FSS on mobilization of salts, nutrients, and metals in urban streams and storm water BMPs by analyzing original data on concentrations and fluxes of salts, nutrients, and metals from 7 urban watersheds in the Mid-Atlantic USA and synthesizing literature data. We also explore future critical research needs through a survey of practitioners and scientists. Our original data show 1) sharp pulses in concentrations of salt ions and metals in urban streams directly following both road salt events and stream restoration construction (e.g.,similar to the way concentrations increase during other soil disturbance activities); 2) sharp declines in pH (acidification) in response to road salt applications because of mobilization of H+ from soil exchange sites by Na+; 3) sharp increases inorganic matter from microbial and algal sources (based on fluorescence spectroscopy) in response to road salt applications, likely because of lysing cells and changes insolubility; 4) substantial retention (~30–40%) of Na+ in stormwater BMP sediments and floodplains in response to salinization; 5) increased ion exchange and mobilization of diverse salt ions (Na+, Ca2+, K+, Mg2+), nutrients(N, P), and trace metals(Cu, Sr) from stormwater BMPs and restored streams in response to FSS; 6) downstream increasing loads ofCl–, SO42–, Br–, F–,andI–along flowpaths through urbanstreams and P release from urban stormwater BMPs in response to salinization; and 7)a substantial annual reduction (>50%) in Na+concentrations in an urban stream when road salt applications were dramatically reduced, which suggests potential for ecosystem recovery. We compare our original results with published metrics of contaminant retention and release across a broad range of stormwater BMPs from North America and Europe.Overall, urban streams and stormwater BMPs consistently retain Na+ and Cl–but mobilize multiple contaminants based on salt types and salinity levels. Finally, we present our top 10 research questions regarding FSS impacts on urban streams and stormwater BMPs. Reducing diverse chemical cocktails of contaminants mobilized by freshwater salinization is a priority for effectively and holistically restoring urban waters. 

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2. Hyporheic hydraulic geometry: Conceptualizing relationships among hyporheic exchange, storage, and water age

   https://doi.org/10.1371/journal.pone.0262080  

   Poole, Geoffrey C.; Fogg, S. Kathleen; O’Daniel, Scott J.; Amerson, Byron E.; Reinhold, Ann Marie; Carlson, Samuel P.; Mohr, Elizabeth J.; Oakland, Hayley C. (January 2022, PLOS ONE)

   Mendoza-Lera, Clara (Ed.)

   Hyporheic exchange is now widely acknowledged as a key driver of ecosystem processes in many streams. Yet stream ecologists have been slow to adopt nuanced hydrologic frameworks developed and applied by engineers and hydrologists to describe the relationship between water storage, water age, and water balance in finite hydrosystems such as hyporheic zones. Here, in the context of hyporheic hydrology, we summarize a well-established mathematical framework useful for describing hyporheic hydrology, while also applying the framework heuristically to visualize the relationships between water age, rates of hyporheic exchange, and water volume within hyporheic zones. Building on this heuristic application, we discuss how improved accuracy in the conceptualization of hyporheic exchange can yield a deeper understanding of the role of the hyporheic zone in stream ecosystems. Although the equations presented here have been well-described for decades, our aim is to make the mathematical basis as accessible as possible and to encourage broader understanding among aquatic ecologists of the implications of tailed age distributions commonly observed in water discharged from and stored within hyporheic zones. Our quantitative description of “hyporheic hydraulic geometry,” associated visualizations, and discussion offer a nuanced and realistic understanding of hyporheic hydrology to aid in considering hyporheic exchange in the context of river and stream ecosystem science and management. 

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3. Stormwater best management practices: Experimental evaluation of chemical cocktails mobilized by freshwater salinization syndrome

   https://doi.org/10.3389/fenvs.2023.1020914  

   Galella, Joseph G.; Kaushal, Sujay S.; Mayer, Paul M.; Maas, Carly M.; Shatkay, Ruth R.; Stutzke, Robert A. (April 2023, Frontiers in Environmental Science)

   Freshwater Salinization Syndrome (FSS) refers to the suite of physical, biological, and chemical impacts of salt ions on the degradation of natural, engineered, and social systems. Impacts of FSS on mobilization of chemical cocktails has been documented in streams and groundwater, but little research has focused on the effects of FSS on stormwater best management practices (BMPs) such as: constructed wetlands, bioswales, ponds, and bioretention. However emerging research suggests that stormwater BMPs may be both sources and sinks of contaminants, shifting seasonally with road salt applications. We conducted lab experiments to investigate this premise; replicate water and soil samples were collected from four distinct stormwater feature types (bioretention, bioswale, constructed wetlands and retention ponds) and were used in salt incubation experiments conducted under six different salinities with three different salts (NaCl, CaCl₂, and MgCl₂). Increased salt concentrations had profound effects on major and trace element mobilization, with all three salts showing significant positive relationships across nearly all elements analyzed. Across all sites, mean salt retention was 34%, 28%, and 26% for Na⁺, Mg²⁺and Ca²⁺respectively, and there were significant differences among stormwater BMPs. Salt type showed preferential mobilization of certain elements. NaCl mobilized Cu, a potent toxicant to aquatic biota, at rates over an order of magnitude greater than both CaCl₂and MgCl₂. Stormwater BMP type also had a significant effect on elemental mobilization, with ponds mobilizing significantly more Mn than other sites. However, salt concentration and salt type consistently had significant effects on mean concentrations of elements mobilized across all stormwater BMPs (p< 0.05), suggesting that processes such as ion exchange mobilize metals mobilize metals and salt ions regardless of BMP type. Our results suggest that decisions regarding the amounts and types of salts used as deicers can have significant effects on reducing contaminant mobilization to freshwater ecosystems. 

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4. Environmental Justice and Stormwater Management: An East Tampa Case Study Towards Equitable Decision Making.

   Carrasquillo, M; Trotz, M (January 2019, National Alliance for Broader Impacts)

   African American communities experience higher incidences of health disparities due to inequitable exposures to environmental stressors. With the increase of climate threats, stormwater runoff and flooding are major concerns that can be linked to environmental injustice in African American communities, including illegal dumping, and even proximity to major highways. Efforts to improve stormwater ( management overlap with efforts to increase green space through the implementation of urban green infrastructure ( presenting the opportunity for UGIUGIto be utilized as a measure to improve geographical and social equity. However there are still many communities who have yet to transition into using green infrastructure for SW management and research is limited on how equitable current stormwater best management practices(SW BMPs) are, particularly in regards to management processes and decisions . The goal of this research is to characterize SW infrastructure in an African American community in Tampa, East Tampa, through the lens of sustainability and environmental justice to better inform management practices towards equitable management of SW infrastructure in the community. 

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5. Evaluating Instream Restoration Effectiveness in Reducing Nitrogen Export from an Urban Catchment with a Data‐Model Approach

   https://doi.org/10.1111/1752-1688.12922  

   Lin, Laurence; Reisinger, Alexander J.; Rosi, Emma J.; Groffman, Peter M.; Band, Lawrence E. (May 2021, JAWRA Journal of the American Water Resources Association)

   Abstract Urbanization increases stormwater runoff into streams, resulting in channel erosion, and increases in sediment and nutrient delivery to receiving water bodies. Stream restoration is widely used as a Best Management Practice to stabilize banks and reduce sediment and nutrient loads. While most instream nutrient retention measurements are often limited to low flow conditions, most of the nutrient load is mobilized at high stream flows in urban settings. We, therefore, use a process‐based stream ecosystem model in conjunction with measurements at low flows and focus on estimation of stream nitrogen retention over the full streamflow distribution. The model provides a theoretical framework to evaluate the geomorphic, hydrologic, and ecological factors that are manipulated by stream restoration, and drive nitrogen retention. We set a model for a pool‐riffle sequence restored stream (190 m) in Baltimore County, Maryland and calibrated the model to thein situmeasured primary production (Nash–Sutcliffe model efficiency coefficient [NSE] NSE = 0.89), respiration (NSE = 0.74), and nitrate uptake lengths (R² = 0.88). At the daily scale, simulations showed low nitrogen retention during high flows due to high transport rates, mobilization of stored hyporheic nitrogen, and scouring of periphyton biomass. This result underscores the need to reduce contributing watershed runoff flashiness to promote aquatic nutrient cycling and retention. At monthly and yearly time scale, model predicted a higher percent reduction in summer than in winter and estimated 5.7%–9.5% of annual nitrate reductions. While the model was tested in a pool‐riffle sequence restoration design, the approach can be adapted to evaluate a range of channel restoration design characteristics, and the effects of upland watershed restoration to mitigate stormwater loading through both restored and unrestored streams. 

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