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Bubbles play a ubiquitous role in electrochemical gas evolution reactions. However, a mechanistic understanding of how bubbles affect the energy efficiency of electrochemical processes remains limited to date, impeding effective approaches to further boost the performance of gas evolution systems. From a perspective of the analogy between heat and mass transfer, bubbles in electrochemical gas evolution reactions exhibit highly similar dynamic behaviors to them in the liquid–vapor phase change. Recent developments of liquid–vapor phase change systems have substantially advanced the fundamental knowledge of bubbles, leading to unprecedented enhancement of heat transfer performance. In this Review, we aim to elucidate a promising opportunity of understanding bubble dynamics in electrochemical gas evolution reactions through a lens of phase change heat transfer. We first provide a background about key parallels between electrochemical gas evolution reactions and phase change heat transfer. Then, we discuss bubble dynamics in gas evolution systems across multiple length scales, with an emphasis on exciting research problems inspired by new insights gained from liquid–vapor phase change systems. Lastly, we review advances in engineered surfaces for manipulating bubbles to enhance heat and mass transfer, providing an outlook on the design of high-performance gas evolving electrodes.
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Harnessing bubble behaviors for developing new analytical strategies
Gas bubbles are easily accessible and offer many unique characteristic properties of a gas/liquid two-phase system for developing new analytical methods. In this minireview, we discuss the newly developed analytical strategies that harness the behaviors of bubbles. Recent advancements include the utilization of the gas/liquid interfacial activity of bubbles for detection and preconcentration of surface-active compounds; the employment of the gas phase properties of bubbles for acoustic imaging and detection, microfluidic analysis, electrochemical sensing, and emission spectroscopy; and the application of the mass transport behaviors at the gas/liquid interface in gas sensing, biosensing, and nanofluidics. These studies have demonstrated the versatility of gas bubbles as a platform for developing new analytical strategies.
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- Award ID(s):
- 1943737
- PAR ID:
- 10201074
- Date Published:
- Journal Name:
- The Analyst
- ISSN:
- 0003-2654
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/D0AN01497D
