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  • Bending good beats breaking bad: phase separation patterns in individual cathode particles upon lithiation and delithiation
Title: Bending good beats breaking bad: phase separation patterns in individual cathode particles upon lithiation and delithiation
The operation of a Li-ion battery involves a concerted sequence of mass and charge transport processes, which are underpinned by alternating dilation/contraction of the active electrode materials. Several Li-ion battery failure mechanisms can be directly traced to lattice-mismatch strain arising from local compositional heterogeneities. The mechanisms of chemo-mechanical coupling that effect phase separation and the resulting complex evolution of internal stress fields remain inadequately understood. This work employs X-ray microscopy techniques to image the evolution of composition and stress across individual bent V 2 O 5 particles. Experimental findings show that lattice strain imposed by the deformation of an individual cathode particle profoundly modifies phase separation patterns, yielding striated Li-rich domains ensconced within a Li-poor matrix. Particle-level inhomogeneities compound across scales resulting in fracture and capacity fade. Coupled phase field modeling of the evolution of domains reveals that the observed patterns minimize the energetic costs incurred by the geometrically imposed strain gradients during lithiation of the material and illustrate that phase separation motifs depend sensitively on the particle geometry, dimensions, interfacial energetics, and lattice incommensurability. Sharp differences in phase separation patterns are observed between lithiation and delithiation. This work demonstrates the promise of strain-engineering and particle geometry to deterministically control phase separation motifs such as to minimize accumulated stresses and mitigate important degradation mechanisms.  more » « less
Award ID(s):
1944674
PAR ID:
10213764
Author(s) / Creator(s):
; ; ; ; ; ; ; ;
Date Published:
Journal Name:
Materials Horizons
Volume:
7
Issue:
12
ISSN:
2051-6347
Page Range / eLocation ID:
3275 to 3290
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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